NMR study on dynamics of protons in Rb3H(SeO4)2

被引:0
|
作者
Matsuo, Y [1 ]
Takahashi, K [1 ]
Hisada, K [1 ]
Ikehata, S [1 ]
机构
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Phys, Shinjuku Ku, Tokyo 1628601, Japan
关键词
Rb3H(SeO4)(2); NMR; ferroelastic phase transition;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Proton NMR spectra were measured in the region from 300K to 500K, in order to clear the proton dynamics in the a(h)-b(h) plane of hexagonal system in paraelastic phase for Rb3H(SeO4)(2), directly. It was found from the NMR spectra that the hydrogen bonds between SeO(4)ions should be broken with the rearrangement process in the a(h)-b(h) plane above T-c. Moreover, from the analysis of the second and forth moments, we determined the area of proton motion in the a(h)-b(h) plane.
引用
收藏
页码:1237 / 1244
页数:8
相关论文
共 50 条
  • [21] PHASE-TRANSITIONS AND PROTON CONDUCTIVITY IN RB3H(SEO4)2 CRYSTALS
    BARANOV, AI
    MAKAROVA, IP
    MURADYAN, LA
    TREGUBCHENKO, AV
    SHUVALOV, LA
    SIMONOV, VI
    KRISTALLOGRAFIYA, 1987, 32 (03): : 682 - 694
  • [22] Raman scattering study of Rb3H(SeO4)2 single crystal in high temperature phases
    Matsumoto, Y
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1998, 67 (07) : 2215 - 2217
  • [23] THE IMPROPER FERROELASTIC PHASE-TRANSITION IN SUPERIONIC RB3H(SEO4)2 CRYSTALS
    PLAKIDA, NM
    SALEJDA, W
    PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1988, 148 (02): : 473 - 481
  • [24] MICROWAVE STUDIES OF DIELECTRIC-PROPERTIES OF SUPERIONIC CRYSTALS OF RB3H(SEO4)2
    MIZERIS, R
    SUETA, A
    URBONAVICHUS, V
    GRIGAS, J
    SHUVALOV, LA
    KRISTALLOGRAFIYA, 1991, 36 (03): : 693 - 698
  • [25] Conductivity properties of Rb3H(SeO4)2 crystals in the region of superionic phase transition
    Sobiestianskas, Ricardas
    Banys, Juras
    Grigas, Jonas
    Pawlowski, Antoni
    SOLID STATE IONICS, 2008, 179 (1-6) : 213 - 217
  • [26] BRILLOUIN-SCATTERING AND DISPERSION OF THE SOUND-VELOCITY IN RB3H(SEO4)2
    LUSHNIKOV, SG
    SHUVALOV, LA
    FERROELECTRICS, 1991, 124 (1-4) : 409 - 414
  • [27] Pretransitional effects at the superionic phase transition of Rb3H(SeO4)2 protonic conductor
    Pawlowski, A
    Szczesniak, L
    Polomska, M
    Hilczer, B
    Kirpichnikova, L
    SOLID STATE IONICS, 2003, 157 (1-4) : 203 - 208
  • [28] STRUCTURAL PHASE-TRANSITIONS IN RB3H(SEO4)2 SINGLE-CRYSTALS
    MAKAROVA, IP
    SHUVALOV, LA
    SIMONOV, VI
    FERROELECTRICS, 1988, 79 : 405 - 410
  • [29] Electric conductivity and proton motion below superionic transition on Rb3H(SeO4)2
    Matsuo, Y
    Takahashi, K
    Ikehata, S
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2001, 70 (10) : 2934 - 2938
  • [30] STRUCTURAL STUDY OF THE HIGH AND LOW-TEMPERATURE PHASES OF THE PROTON CONDUCTOR RB3H(SEO4)(2)
    BOHN, A
    MELZER, R
    SONNTAG, R
    LECHNER, RE
    SCHUCK, G
    LANGER, K
    SOLID STATE IONICS, 1995, 77 : 111 - 117