Ruthenium(III) acetylacetonate [Ru(acac)3] -: An efficient recyclable catalyst for the acetylation of phenols, alcohols, and amines under neat conditions

被引:17
|
作者
Varala, Ravi [1 ]
Nasreen, Aayesha [1 ]
Adapa, Srinivas R. [1 ]
机构
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
关键词
acetylation; protecting groups; ruthenium(III) acetylacetonate; phenols; alcohols; amines;
D O I
10.1139/V06-191
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A catalytic amount of ruthenium(III) acetylacetonate (2 mol%) [Ru(acac)(3)] enables solvent-free acetylation of phenols, alcohols, and amines at ambient temperature in good to excellent yields. Furthermore, the catalyst could be recovered and reused at least three times without a significant loss in yields.
引用
收藏
页码:148 / 152
页数:5
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