Ruthenium(III) acetylacetonate [Ru(acac)3] -: An efficient recyclable catalyst for the acetylation of phenols, alcohols, and amines under neat conditions

被引：17
|
作者：
Varala, Ravi [1 ]
Nasreen, Aayesha [1 ]
Adapa, Srinivas R. [1 ]
机构：
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2007年 / 85卷 / 02期
关键词：
acetylation; protecting groups; ruthenium(III) acetylacetonate; phenols; alcohols; amines;
D O I：
10.1139/V06-191
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A catalytic amount of ruthenium(III) acetylacetonate (2 mol%) [Ru(acac)(3)] enables solvent-free acetylation of phenols, alcohols, and amines at ambient temperature in good to excellent yields. Furthermore, the catalyst could be recovered and reused at least three times without a significant loss in yields.
引用
收藏
页码：148 / 152
页数：5
相关论文
共 50 条
  • [21] Chloroferrate(III) Ionic Liquid as Recyclable Catalyst for the Acetylation of Alcohols and Phenols and for 1,1-Diacylation of Aldehydes
    Wang, Dong-Sheng
    Li, Gui-Yun
    Peng, Yan-Qing
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2009, 56 (04) : 834 - 838
  • [22] Synthesis of task-specific imidazolium ionic liquid as an efficient catalyst in acetylation of alcohols, phenols, and amines
    Chaubey, Snehkrishn A.
    Mishra, Roli
    CHEMICAL PAPERS, 2020, 74 (10): : 3259 - 3268
  • [23] Synthesis of task-specific imidazolium ionic liquid as an efficient catalyst in acetylation of alcohols, phenols, and amines
    Snehkrishn A. Chaubey
    Roli Mishra
    Chemical Papers, 2020, 74 : 3259 - 3268
  • [24] HIGHLY EFFICIENT AND VERSATILE ACETYLATION OF ALCOHOLS, PHENOLS AND AMINES CATALYZED BY METHYLENEDIPHOSPHONIC ACID (MDP) UNDER SOLVENT-FREE CONDITIONS
    Xie, Minhao
    Wang, Hongyong
    Wu, Jun
    He, Yongjun
    Liu, Yaling
    Zou, Pei
    JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2011, 56 (04): : 884 - 886
  • [25] A mild and efficient acetylation of alcohols, phenols and amines with acetic anhydride using La(NO3)3•6H2O as a catalyst under solvent-free conditions
    Reddy, T. Srikanth
    Narasimhulu, M.
    Suryakiran, N.
    Mahesh, K. Chinni
    Ashalatha, K.
    Venkateswarlu, Y.
    TETRAHEDRON LETTERS, 2006, 47 (38) : 6825 - 6829
  • [26] Doping of copper (I) oxide onto a solid support as a recyclable catalyst for acetylation of amines/alcohols/phenols and synthesis of trisubstituted imidazole
    Gupta, Manjulla
    Gupta, Monika
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2016, 13 (02) : 231 - 241
  • [27] Doping of copper (I) oxide onto a solid support as a recyclable catalyst for acetylation of amines/alcohols/phenols and synthesis of trisubstituted imidazole
    Manjulla Gupta
    Monika Gupta
    Journal of the Iranian Chemical Society, 2016, 13 : 231 - 241
  • [28] P2O5/Al2O3 as an Efficient Heterogeneous Catalyst for the Acetylation of Alcohols, Phenols, Thiols, and Amines Under Solvent-Free Conditions
    Zarei, Amin
    Hajipour, Abdol R.
    Khazdooz, Leila
    SYNTHETIC COMMUNICATIONS, 2011, 41 (12) : 1772 - 1785
  • [29] In situ generated acylimidazolium acetate as an efficient catalyst and acylating agent for the acetylation of alcohols, phenols, and amines at ambient temperature
    Nowrouzi, Najmeh
    Alizadeh, Seyedeh Zahra
    CHINESE JOURNAL OF CATALYSIS, 2013, 34 (09) : 1787 - 1790
  • [30] Catalytic acetylation of alcohols, phenols, thiols and amines with zeolite H-FER under solventless conditions
    Chavan, SP
    Anand, R
    Pasupathy, K
    Rao, BS
    GREEN CHEMISTRY, 2001, 3 (06) : 320 - 322
12345