Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

被引：13

作者：

Maeda, Yutaka ^{[1
]}

Kimura, Masato ^{[2
]}

Ueda, Chihiro ^{[1
]}

Yamada, Michio ^{[1
]}

Kikuchi, Toru ^{[1
]}

Suzuki, Mitsuaki ^{[1
]}

Wang, Wei-Wei ^{[3
]}

Mizorogi, Naomi ^{[2
]}

Karousis, Nikolaos ^{[4
]}

Tagmatarchis, Nikos ^{[4
]}

Hasegawa, Tadashi ^{[1
]}

Olmstead, Marilyn M. ^{[5
]}

Balch, Alan L. ^{[5
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,2
,6
,7
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Tsukuba, Life Sci Ctr, Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan

[4] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[5] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[6] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Peoples R China

[7] Fdn Advancement Int Sci, Tsukuba, Ibaraki 3050821, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 83期

基金：

美国国家科学基金会;

关键词：

ENDOHEDRAL METALLOFULLERENES; ELECTROCHEMICAL PROPERTIES; THERMOCHEMICAL KINETICS; DENSITY FUNCTIONALS; M3N-AT-C-80; M; REACTIVITY; I-H-SC3N-AT-C-80; CYCLOADDITION; SC3N-AT-C-80; DERIVATIVES;

D O I：

10.1039/c4cc04946b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of Sc3N@I-h-C-80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I-h-C-80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

引用

页码：12552 / 12555

页数：4

共 50 条

[41] W(CO)3(Ph2PC2H4PPh2)(η2-Sc3N@Ih-C80/Sc3N@D5h-C80): regioselective synthesis and crystallographic characterization of air-stable mononuclear complexes of endohedral fullerenes
Bao, Lipiao
Liu, Bin
Li, Xiaofang
Pan, Changwang
Xie, Yunpeng
Lu, Xing
DALTON TRANSACTIONS, 2016, 45 (29) : 11606 - 11610
[42] Prato Reaction of M3N@Ih-C80 (M = Sc, Lu, Y, Gd) with Reversible Isomerization
Aroua, Safwan
Yamakoshi, Yoko
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (50) : 20242 - 20245
[43] Fluxional behaviour of Sc3 n in endohedral Sc3N@C80
Vietze, K
Seifert, G
STRUCTURAL AND ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES, 2002, 633 : 39 - 42
[44] Isolation and structural characterization of the endohedral fullerene Sc3N@C78
Olmstead, MM
de Bettencourt-Dias, A
Duchamp, JC
Stevenson, S
Marciu, D
Dorn, HC
Balch, AL
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (07) : 1223 - +
[45] Reactivity differences of Sc3N@C2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80
Ceron, Maira R.
Izquierdo, Marta
Alegret, Nuria
Valdez, Juan A.
Rodriguez-Fortea, Antonio
Olmstead, Marilyn M.
Balch, Alan L.
Poblet, Josep M.
Echegoyen, Luis
CHEMICAL COMMUNICATIONS, 2016, 52 (01) : 64 - 67
[46] Radical trifluoromethylation of Sc3N@C80
Shustova, Natalia B.
Popov, Alexey A.
Mackey, Mary A.
Coumbe, Curtis E.
Phillips, J. Paige
Stevenson, Steven
Strauss, Steven H.
Boltalina, Olga V.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (38) : 11676 - +
[47] Synthesis and Electrochemical Studies of Bingel-Hirsch Derivatives of M3N@Ih-C80 (M = Sc, Lu)
Pinzon, Julio R.
Zuo, Tianming
Echegoyen, Luis
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (16) : 4864 - 4869
[48] Endohedral Metal-Induced Regioselective Formation of Bis-Prato Adduct of Y3N@Ih-C80 and Gd3N@Ih-C80
Aroua, Safwan
Garcia-Borras, Marc
Boelter, Marc Florian
Osuna, Silvia
Yamakoshi, Yoko
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (01) : 58 - 61
[49] Photoinduced Charge Transfer and Electrochemical Properties of Triphenylamine Ih-Sc3N@C80 Donor-Acceptor Conjugates
Pinzon, Julio R.
Gasca, Diana C.
Sankaranarayanan, Shankara G.
Bottari, Giovanni
Torres, Tomas
Guldi, Dirk M.
Echegoyen, Luis
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) : 7727 - 7734
[50] Isolation and structural characterization of a family of endohedral fullerenes including the large, chiral cage fullerenes Tb3N@C88 and Tb3N@C86 as well as the Ih and D5h isomers of Tb3N@C80
Zuo, Tianming
Beavers, Christine M.
Duchamp, James C.
Campbell, Anne
Dorn, Harry C.
Olmstead, Marilyn M.
Balch, Alan L.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) : 2035 - 2043

← 1 2 3 4 5 →