Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

被引：13

作者：

Maeda, Yutaka ^{[1
]}

Kimura, Masato ^{[2
]}

Ueda, Chihiro ^{[1
]}

Yamada, Michio ^{[1
]}

Kikuchi, Toru ^{[1
]}

Suzuki, Mitsuaki ^{[1
]}

Wang, Wei-Wei ^{[3
]}

Mizorogi, Naomi ^{[2
]}

Karousis, Nikolaos ^{[4
]}

Tagmatarchis, Nikos ^{[4
]}

Hasegawa, Tadashi ^{[1
]}

Olmstead, Marilyn M. ^{[5
]}

Balch, Alan L. ^{[5
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,2
,6
,7
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Tsukuba, Life Sci Ctr, Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan

[4] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[5] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[6] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Peoples R China

[7] Fdn Advancement Int Sci, Tsukuba, Ibaraki 3050821, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 83期

基金：

美国国家科学基金会;

关键词：

ENDOHEDRAL METALLOFULLERENES; ELECTROCHEMICAL PROPERTIES; THERMOCHEMICAL KINETICS; DENSITY FUNCTIONALS; M3N-AT-C-80; M; REACTIVITY; I-H-SC3N-AT-C-80; CYCLOADDITION; SC3N-AT-C-80; DERIVATIVES;

D O I：

10.1039/c4cc04946b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of Sc3N@I-h-C-80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I-h-C-80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

引用

页码：12552 / 12555

页数：4

共 50 条

[31] On the stabilization of Sc3C@Ih (31924)-C80 by functionalization of fluorine
Zhao, Yao-Xiao
Zhao, Xiang
CHEMICAL PHYSICS LETTERS, 2020, 759
[32] An Efficient Method to Separate Sc3N@C80 Ih and D5h Isomers and Sc3N@C78 by Selective Oxidation with Acetylferrocenium [Fe(COCH3C5H4)Cp]+
Ceron, Maira R.
Li, Fang-Fang
Echegoyen, Luis
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (23) : 7410 - 7415
[33] Synthesis and Charge-Transfer Chemistry of La2@Ih-C80/Sc3N@Ih-C80Zinc-Porphyrin Conjugates: Impact of Endohedral Cluster
Feng, Lai
Radhakrishnan, Shankara Gayathri
Mizorogi, Naomi
Slanina, Zdenek
Nikawa, Hidefumi
Tsuchiya, Takahiro
Akasaka, Takeshi
Nagase, Shigeru
Martin, Nazario
Guldi, Dirk M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (19) : 7608 - 7618
[34] Aromatic tripodal receptors for (C60-Ih)[5,6]fullerene
Dell'Anna, Gian Maria
Annunziata, Rita
Benaglia, Maurizio
Celentano, Giuseppe
Cozzi, Franco
Francesconi, Oscar
Roelens, Stefano
ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (18) : 3871 - 3877
[35] Photoreactions of Sc3N@C80 with Disilirane, Silirane, and Digermirane: A Photochemical Method to Separate Ih and D5h Isomers
Kako, Masahiro
Miyabe, Kyosuke
Fukazawa, Shinpei
Kanzawa, Shinji
Yasui, Masanori
Yamada, Michio
Maeda, Yutaka
Slanina, Zdenek
Uhlik, Filip
Adamowicz, Ludwik
Papadopoulos, Ilias
Guldi, Dirk M.
Furukawa, Makoto
Nagase, Shigeru
Akasaka, Takeshi
PHOTOCHEM, 2022, 2 (01): : 122 - 137
[36] Sc3N@Ih-C80 as a novel Lewis acid to trap abnormal N-heterocyclic carbenes: the unprecedented formation of a singly bonded [6,6,6]-adduct
Chen, Muqing
Bao, Lipiao
Ai, Min
Shen, Wangqiang
Lu, Xing
CHEMICAL SCIENCE, 2016, 7 (03) : 2331 - 2334
[37] Characterization of the bis-silylated endofullerene Sc3N@C80
Wakahara, Takatsugu
Iiduka, Yuko
Ikenaga, Ozora
Nakahodo, Tsukasa
Sakuraba, Akihiro
Tsuchiya, Takahiro
Maeda, Yutaka
Kako, Masahiro
Akasaka, Takeshi
Yoza, Kenji
Horn, Ernst
Mizorogi, Naomi
Nagase, Shigeru
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) : 9919 - 9925
[38] Characterization of the bis-silylated endofullerene Sc3N@C 80
Wakahara, Takatsugu
Iiduka, Yuko
Ikenaga, Ozora
Nakahodo, Tsukasa
Sakuraba, Akihiro
Tsuchiya, Takahiro
Maeda, Yutaka
Kako, Masahiro
Akasaka, Takeshi
Yoza, Kenji
Horn, Ernst
Mizorogi, Naomi
Nagase, Shigeru
Journal of the American Chemical Society, 2006, 128 (30): : 9919 - 9925
[39] Dancing on a fullerene surface:: Isomerization of Y3N@(N-ethylpyrrolidino-C80) from the 6,6 to the 5,6 regioisomer
Rodriguez-Fortea, Antonio
Campanera, Josep M.
Cardona, Claudia M.
Echegoyen, Luis
Poblet, Josep M.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) : 8176 - 8180
[40] Isolation and characterization of the endohedral metallofullerene Tb3N@C80
Feng, L
Xu, JX
Shi, ZJ
He, XR
Gu, ZN
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (06): : 996 - 998

← 1 2 3 4 5 →