Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

被引：13

作者：

Maeda, Yutaka ^{[1
]}

Kimura, Masato ^{[2
]}

Ueda, Chihiro ^{[1
]}

Yamada, Michio ^{[1
]}

Kikuchi, Toru ^{[1
]}

Suzuki, Mitsuaki ^{[1
]}

Wang, Wei-Wei ^{[3
]}

Mizorogi, Naomi ^{[2
]}

Karousis, Nikolaos ^{[4
]}

Tagmatarchis, Nikos ^{[4
]}

Hasegawa, Tadashi ^{[1
]}

Olmstead, Marilyn M. ^{[5
]}

Balch, Alan L. ^{[5
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,2
,6
,7
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Tsukuba, Life Sci Ctr, Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan

[4] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[5] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[6] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Peoples R China

[7] Fdn Advancement Int Sci, Tsukuba, Ibaraki 3050821, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 83期

基金：

美国国家科学基金会;

关键词：

ENDOHEDRAL METALLOFULLERENES; ELECTROCHEMICAL PROPERTIES; THERMOCHEMICAL KINETICS; DENSITY FUNCTIONALS; M3N-AT-C-80; M; REACTIVITY; I-H-SC3N-AT-C-80; CYCLOADDITION; SC3N-AT-C-80; DERIVATIVES;

D O I：

10.1039/c4cc04946b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of Sc3N@I-h-C-80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I-h-C-80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

引用

页码：12552 / 12555

页数：4

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