A novel layered material of LiNi0.32Mn0.33Co0.33Al0.01O2 for advanced lithium-ion batteries

被引：47
|
作者：
Wu, Feng [1 ,2 ]
Wang, Meng [1 ,2 ]
Su, Yuefeng [1 ,2 ]
Bao, Liying [1 ,2 ]
Chen, Shi [1 ,2 ]
机构：
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
[2] Natl Dev Ctr High Technol Green Mat, Beijing 100081, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2010年 / 195卷 / 09期
关键词：
Cathode material; Al substitution; Li-ion battery; Cycling performance; ELECTROCHEMICAL PROPERTIES; CATHODE MATERIALS; PERFORMANCE; LICOO2; AL; R(3)OVER-BAR-M; ALUMINUM; LINIO2; CO; TI;
D O I：
10.1016/j.jpowsour.2009.11.041
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel layered material of LiNi0.32Mn0.33Co0.33Al0.01O2 with alpha-NaFeO2 structure is synthesized by sol-gel method. X-ray diffraction (XRD) shows that the cation mixing in the Li layers of it is decreased. in addition, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are employed to characterize the reaction of lithium-ion insertion and extraction from materials. The results indicate that the structure of LiNi0.32Mn0.33Co0.33Al0.01O2 is more stable than that of the LiNi0.33Mn0.33Co0.33O2. The capacity retention of LiNi0.33Mn0.33Co0.33O2. after 40 cycles at 2.0 C is only 89.9%, however, that of the LiNi0.32Mn0.33Co0.33Al0.01O2 is improved to 97.1%. The capacity of the LiNi0.32Mn0.33Co0.33Al0.01O2 at 4.0 C remains 71.8% of the capacity at 0.2 C, while that of the LiNi0.33Mn0.33Co0.33O2 is only 54.3%. EIS measurement reveals that the increase in the charge transfer resistance during cycling is suppressed in the LiNi0.32Mn0.33Co0.33Al0.01O2 material. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：2900 / 2904
页数：5
相关论文
共 50 条
  • [31] Exploration of PVP-Combustion Synthesis and Electrochemical Performance of O3-type NaxNi0.33Fe0.33Mn0.33O2 Layered Material for Sodium-Ion Batteries
    Xu, Manyang
    Zhang, Yanli
    Shao, Weiwei
    Li, Xiaoning
    Zhou, Jiakun
    Zhou, Wenzhang
    Zhang, Wenjuan
    Feng, Yan
    Zhang, Ding
    Dai, Kehua
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2024, 171 (01)
  • [32] A Novel Perspective on Surface Modification of LiNi0.5Co0.2Mn0.3O2 Cathode Material for Lithium-Ion Batteries
    Zhang, Yang
    Song, Ye
    Liu, Lin
    Ma, Juanjuan
    Liu, Jie
    CHEMELECTROCHEM, 2022, 9 (18)
  • [33] Ni0.33Mn0.33Co0.33Fe2O4 nanoparticles anchored on oxidized carbon nanotubes as advanced anode materials in Li-ion batteries
    Zhang, Zailei
    Kan, Guangwei
    Ren, Wenfeng
    Tan, Qiangqiang
    Zhong, Ziyi
    Su, Fabing
    RSC ADVANCES, 2014, 4 (64) : 33769 - 33775
  • [34] Improved electrochemical performance of the LiNi0.8Co0.1Mn0.1O2 material with lithium-ion conductor coating for lithium-ion batteries
    Wang, Meng
    Zhang, Ran
    Gong, Yongqiang
    Su, Yuefeng
    Xiang, Debo
    Chen, Lin
    Chen, Yunbo
    Luo, Min
    Chu, Mo
    SOLID STATE IONICS, 2017, 312 : 53 - 60
  • [35] Lithium-ion conductor LiAlO2 coated LiNi0.8Mn0.1Co0.1O2 as cathode material for lithium-ion batteries
    Huang, Bing
    Zhao, Zhiyuan
    Sun, Yuzhen
    Wang, Meng
    Chen, Lin
    Gu, Yijie
    SOLID STATE IONICS, 2019, 338 : 31 - 38
  • [36] Dual modification of LiNi0.95Co0.04Mn0.01O2 for enhancing its cycling stability in lithium-ion batteries
    Ni, Wenhao
    Li, Xinze
    Huang, Bin
    Sheng, Ao
    Jia, Xiaotong
    Li, Yanwei
    Yang, Jianwen
    MATERIALS LETTERS, 2023, 333
  • [37] Anion doping of LiNi0.4Co0.2Mn0.4O2 cathode material for lithium-ion batteries
    Zhang, Hailang, 1600, Science Press (43):
  • [38] Silver Nanocoating of LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries
    Li, Xintong
    Chang, Kai
    Abbas, Somia M.
    El-Tawil, Rasha S.
    Abdel-Ghany, Ashraf E.
    Hashem, Ahmed M.
    Wang, Hua
    Coughlin, Amanda L.
    Zhang, Shixiong
    Mauger, Alain
    Zhu, Likun
    Julien, Christian M.
    MICROMACHINES, 2023, 14 (05)
  • [39] Layered lithium insertion material of LiNi1/2Mn1/2O2:: A possible alternative to LiCoO2 for advanced lithium-ion batteries
    Ohzuku, T
    Makimura, Y
    CHEMISTRY LETTERS, 2001, (08) : 744 - 745
  • [40] Anion Doping of LiNi0.4Co0.2Mn0.4O2 Cathode Material for Lithium-Ion Batteries
    Yang Wei
    Zhang Hailang
    RARE METAL MATERIALS AND ENGINEERING, 2014, 43 (12) : 3133 - 3137
12345