A novel layered material of LiNi0.32Mn0.33Co0.33Al0.01O2 for advanced lithium-ion batteries

被引:47
|
作者
Wu, Feng [1 ,2 ]
Wang, Meng [1 ,2 ]
Su, Yuefeng [1 ,2 ]
Bao, Liying [1 ,2 ]
Chen, Shi [1 ,2 ]
机构
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
[2] Natl Dev Ctr High Technol Green Mat, Beijing 100081, Peoples R China
关键词
Cathode material; Al substitution; Li-ion battery; Cycling performance; ELECTROCHEMICAL PROPERTIES; CATHODE MATERIALS; PERFORMANCE; LICOO2; AL; R(3)OVER-BAR-M; ALUMINUM; LINIO2; CO; TI;
D O I
10.1016/j.jpowsour.2009.11.041
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel layered material of LiNi0.32Mn0.33Co0.33Al0.01O2 with alpha-NaFeO2 structure is synthesized by sol-gel method. X-ray diffraction (XRD) shows that the cation mixing in the Li layers of it is decreased. in addition, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are employed to characterize the reaction of lithium-ion insertion and extraction from materials. The results indicate that the structure of LiNi0.32Mn0.33Co0.33Al0.01O2 is more stable than that of the LiNi0.33Mn0.33Co0.33O2. The capacity retention of LiNi0.33Mn0.33Co0.33O2. after 40 cycles at 2.0 C is only 89.9%, however, that of the LiNi0.32Mn0.33Co0.33Al0.01O2 is improved to 97.1%. The capacity of the LiNi0.32Mn0.33Co0.33Al0.01O2 at 4.0 C remains 71.8% of the capacity at 0.2 C, while that of the LiNi0.33Mn0.33Co0.33O2 is only 54.3%. EIS measurement reveals that the increase in the charge transfer resistance during cycling is suppressed in the LiNi0.32Mn0.33Co0.33Al0.01O2 material. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2900 / 2904
页数:5
相关论文
共 50 条
  • [21] Characterization of NaxLi0.67+yNi0.33Mn0.67O2 as a positive electrode material for lithium-ion batteries
    Chiba, K.
    Shikano, M.
    Sakaebe, H.
    RSC ADVANCES, 2018, 8 (46) : 26335 - 26340
  • [22] Correlation between the structural, electrical and electrochemical performance of layered Li(Ni0.33Co0.33Mn0.33)O2 for lithium ion battery
    P. Senthil Kumar
    A. Sakunthala
    M. V. Reddy
    S. Shanmugam
    M. Prabu
    Journal of Solid State Electrochemistry, 2016, 20 : 1865 - 1876
  • [23] Correlation between the structural, electrical and electrochemical performance of layered Li(Ni0.33Co0.33Mn0.33)O2 for lithium ion battery
    Kumar, P. Senthil
    Sakunthala, A.
    Reddy, M. V.
    Shanmugam, S.
    Prabu, M.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2016, 20 (07) : 1865 - 1876
  • [24] Investigation of hysteresis and relaxation behaviour in graphite and LiNi0.33Mn0.33Co0.33O2 electrodes
    Rashid, Muhammad
    Pathan, Tanveerkhan S.
    McGordon, Andrew
    Kendrick, Emma
    Widanage, W. D.
    JOURNAL OF POWER SOURCES, 2019, 440
  • [25] Characteristics of twins in Li(Ni0.67Co0.33)O2 as a cathode material for lithium-ion batteries
    Ai, YanLing
    Zhang, M. Q.
    Jiang, F.
    Zhang, Ruizhi
    Liu, Jun
    Wang, C.
    Xiao, W. H.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 791 : 1167 - 1175
  • [26] A short review on layered LiNi0.8Co0.1Mn0.1O2 positive electrode material for lithium-ion batteries
    Ding, Yin
    Wang, Rui
    Wang, Lei
    Cheng, Kailin
    Zhao, Zhikun
    Mu, DaoBin
    Wu, Borong
    8TH INTERNATIONAL CONFERENCE ON APPLIED ENERGY (ICAE2016), 2017, 105 : 2941 - 2952
  • [27] Lithium insertion material of LiNi1/2Mn1/2O2 for advanced lithium-ion batteries
    Makimura, Y
    Ohzuku, T
    JOURNAL OF POWER SOURCES, 2003, 119 : 156 - 160
  • [28] Multiphase LiNi0.33Mn0.54Co0.13O2 Cathode Material with High Capacity Retention for Li-Ion Batteries
    Nayak, Prasant Kumar
    Grinblat, Judith
    Levi, Mikhael
    Haik, Ortal
    Levi, Elena
    Kim, Sangryun
    Choi, Jang Wook
    Aurbach, Doron
    CHEMELECTROCHEM, 2015, 2 (12): : 1957 - 1965
  • [29] Bio-inspired synthesis of xLi2MnO3-(1-x) LiNi0.33Co0.33Mn0.33O2 lithium-rich layered cathode materials
    Hou, Chuanxin
    Oaki, Yuya
    Hosono, Eiji
    Lin, Hong
    Imai, Hiroaki
    Fan, Yuqi
    Dang, Feng
    MATERIALS & DESIGN, 2016, 109 : 718 - 725
  • [30] 真空冷喷涂LiNi0.33Co0.33Mn0.33O2涂层颗粒沉积行为研究
    谢扬
    马凯
    李成新
    杨冠军
    李长久
    热喷涂技术, 2019, 11 (01) : 30 - 36