Palladium-catalyzed coupling reactions of N-methoxy-N-methylcarbamoyl chloride for the synthesis of N-methoxy-N-methylamides

被引：0
|
作者：
Murakami, M [1 ]
Hoshino, Y [1 ]
Ito, H [1 ]
Ito, Y [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 60601, Japan
来源：
CHEMISTRY LETTERS | 1998年 / 02期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new synthetic method of N-methoxy-N-methylamides is developed. The palladium-catalyzed coupling reaction of N-methoxy-N-methylcarbamoyl chloride furnished N-methoxy-N-methylamide in moderate to good yield, wherein a carbonyl equivalent was appended to sp and sp(2) carbon atoms as a versatile synthetic basis for further manipulation.
引用
收藏
页码：163 / 164
页数：2
相关论文
共 50 条
  • [41] Palladium-Catalyzed Carbonylation in the Synthesis of N-Ynonylsulfoximines
    Ma, Ding
    Wang, Chenyang
    Kong, Deshen
    Tu, Yongliang
    Shi, Peng
    Bolm, Carsten
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (05) : 1330 - 1334
  • [42] Palladium-Catalyzed Synthesis of N-Aryl Carbamates
    Vinogradova, Ekaterina V.
    Park, Nathaniel H.
    Fors, Brett P.
    Buchwald, Stephen L.
    ORGANIC LETTERS, 2013, 15 (06) : 1394 - 1397
  • [43] Palladium-Catalyzed Synthesis of N-tert-Prenylindoles
    Johnson, Kirsten F.
    Van Zeeland, Ryan
    Stanley, Levi M.
    ORGANIC LETTERS, 2013, 15 (11) : 2798 - 2801
  • [44] PERSULFATE OXIDATIONS .12. GENERATION AND REACTIONS OF N-METHOXY-BENZAMIDYLS AND N-METHOXY-BENZSULFONAMIDYLS
    FORRESTER, AR
    JOHANSSON, EM
    THOMSON, RH
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (04): : 1112 - 1119
  • [45] Palladium-catalyzed coupling reactions involving N-alkoxyimidoyl halides and boronic acids
    Dolliver, Debra D.
    Poche, Caroline
    Johnson, James E.
    Mckim, Artie S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [46] 4-methoxy-N,N′-diphenylbenzamidine
    Bortoluzzi, AJ
    Echevarria, A
    Rodrigues-Santos, CE
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O1837 - O1839
  • [47] Palladium-catalyzed cascade reactions of benzyl halides with N,N-diallyl-p-toluenesulfonamide
    Wang, Liansheng
    Pan, Yi
    Hu, Hongwen
    HETEROCYCLIC COMMUNICATIONS, 2012, 18 (03) : 147 - 150
  • [48] Palladium-catalyzed regiospecific reactions of N-acylbenzotriazoles with epoxides
    El Khatib, Mirna
    Elagawany, Mohamed
    Todadze, Eka
    Khelashvili, Levan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [49] GEMINAL SYSTEMS .29. REACTIONS OF N-CHLORO-N-METHOXY-N',N'-DIMETHYLUREA WITH N-NUCLEOPHILES
    RUDCHENKO, VF
    SHEVCHENKO, VI
    KOSTYANOVSKII, RG
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1986, 35 (03): : 551 - 554
  • [50] Synthesis of benzannulated N-heterocycles by a palladium-catalyzed C-C/C-N coupling of bromoalkylamines
    Thansandote, Praew
    Raemy, Manuel
    Rudolph, Alena
    Lautens, Mark
    ORGANIC LETTERS, 2007, 9 (25) : 5255 - 5258
12345