Palladium-catalyzed coupling reactions of N-methoxy-N-methylcarbamoyl chloride for the synthesis of N-methoxy-N-methylamides

被引:0
|
作者
Murakami, M [1 ]
Hoshino, Y [1 ]
Ito, H [1 ]
Ito, Y [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 60601, Japan
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new synthetic method of N-methoxy-N-methylamides is developed. The palladium-catalyzed coupling reaction of N-methoxy-N-methylcarbamoyl chloride furnished N-methoxy-N-methylamide in moderate to good yield, wherein a carbonyl equivalent was appended to sp and sp(2) carbon atoms as a versatile synthetic basis for further manipulation.
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页码:163 / 164
页数:2
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