A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system

被引：394
|
作者：
Kawanami, H
Sasaki, A
Matsui, K
Ikushima, Y
机构：
[1] Natl Inst Adv Ind Sci & Technol, Supercrit Fluid Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
[2] JST, CREST, Tokyo, Japan
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 07期
关键词：
D O I：
10.1039/b212823c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.
引用
收藏
页码：896 / 897
页数：2
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