A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system

被引：394
|
作者：
Kawanami, H
Sasaki, A
Matsui, K
Ikushima, Y
机构：
[1] Natl Inst Adv Ind Sci & Technol, Supercrit Fluid Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
[2] JST, CREST, Tokyo, Japan
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 07期
关键词：
D O I：
10.1039/b212823c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.
引用
收藏
页码：896 / 897
页数：2
相关论文
共 50 条
  • [21] Revealing the effect of water on the CO2-ionic liquid system in microchannels: Physical properties, hydrodynamics and mass transfer behavior
    Chen, Yu
    Yang, Yiqian
    Wang, Gang
    Huo, Feng
    Li, Chunshan
    CHEMICAL ENGINEERING SCIENCE, 2025, 301
  • [22] Synthesis and swelling of poly(bisphenol A carbonate) using supercritical CO2
    Univ of North Carolina at Chapel, Hill, Chapel Hill, United States
    Macromolecules, 25 (9090-9092):
  • [23] Synthesis and swelling of poly(bisphenol A carbonate) using supercritical CO2
    Gross, SM
    Givens, RD
    Jikei, M
    Royer, JR
    Khan, S
    DeSimone, JM
    Odell, PG
    Hamer, GR
    MACROMOLECULES, 1998, 31 (25) : 9090 - 9092
  • [24] Non-halogen catalysts for propylene carbonate synthesis from CO2 under supercritical conditions
    Yasuda, H
    He, LN
    Takahashi, T
    Sakakura, T
    APPLIED CATALYSIS A-GENERAL, 2006, 298 : 177 - 180
  • [25] New procedure for recycling homogeneous catalyst:: propylene carbonate synthesis under supercritical CO2 conditions
    He, LN
    Yasuda, H
    Sakakura, T
    GREEN CHEMISTRY, 2003, 5 (01) : 92 - 94
  • [26] Continuous flow synthesis of propylene carbonate using DBU-based ionic liquid in a packed bed reactor
    Sun, Jianfei
    Li, Zhuojian
    Yin, Jianzhong
    Yin, Jianzhong (jzyin@dlut.edu.cn), 1600, Elsevier Ltd (53):
  • [27] Continuous flow synthesis of propylene carbonate using DBU-based ionic liquid in a packed bed reactor
    Sun, Jianfei
    Li, Zhuojian
    Yin, Jianzhong
    JOURNAL OF CO2 UTILIZATION, 2021, 53
  • [28] Propylene carbonate synthesis routes using CO2: DFT and thermodynamic analysis
    Katiyar, Anag
    Kumar, Pankaj
    Srivastava, Vimal Chandra
    Kumar, Vimal
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321
  • [29] Fixation of CO2 by electrocatalytic reduction to synthesis of dimethyl carbonate in ionic liquid using effective silver-coated nanoporous copper composites
    Xuan Yun Wang
    Chinese Chemical Letters, 2010, 21 (08) : 987 - 990
  • [30] Fixation of CO2 by electrocatalytic reduction to synthesis of dimethyl carbonate in ionic liquid using effective silver-coated nanoporous copper composites
    Wang, Xuan Yun
    Liu, Su Qin
    Huang, Ke Long
    Feng, Qiu Ju
    Ye, De Lai
    Liu, Bing
    Liu, Jin Long
    Jin, Guan Hua
    CHINESE CHEMICAL LETTERS, 2010, 21 (08) : 987 - 990
12345