Polymer-supported triphenylphosphine: application in organic synthesis and organometallic reactions

被引:22
|
作者
Moussa, Ziad [1 ]
Judeh, Zaher M. A. [2 ]
Ahmed, Saleh [3 ,4 ]
机构
[1] United Arab Emirates Univ, Coll Sci, Dept Chem, POB 15551, Al Ain, U Arab Emirates
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr,N1-2-B1-14, Singapore 637459, Singapore
[3] Umm Al Qura Univ, Fac Appl Sci, Dept Chem, Mecca 21955, Saudi Arabia
[4] Assiut Univ, Fac Sci, Dept Chem, Assiut 71516, Egypt
关键词
PHOSPHINE-HALOGEN COMPLEXES; SOLID-PHASE SYNTHESIS; ORCHESTRATED MULTISTEP SEQUENCE; PALLADIUM-CATALYZED CYANATION; COBALT CARBONYL-COMPLEXES; CROSS-LINKED POLYSTYRENE; ALPHA-AMINO-ACIDS; FUNCTIONALIZED POLYMERS; ONE-POT; BOUND TRIPHENYLPHOSPHINE;
D O I
10.1039/c9ra07094j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This comprehensive review highlights the diverse chemistry and applications of polymer-supported triphenylphosphine (PS-TPP) in organic synthesis since its inception. Specifically, the review describes applications of the preceding reagent in functional group interconversions, heterocycle synthesis, metal complexes and their application in synthesis, and total synthesis of natural products. Many examples are provided from the literature to show the scope and selectivity (regio, stereo, and chemo) in these transformations.
引用
收藏
页码:35217 / 35272
页数:56
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