Investigation of hydrogenation of Dibenzyltoluene as liquid organic hydrogen carrier

被引:25
|
作者
Ali, Ahsan [1 ]
Kumar, G. Udaya [1 ]
Lee, Hee Joon [1 ]
机构
[1] Kookmin Univ, Dept Mech Engn, Seoul 02707, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Liquid organic hydrogen storage; Raney-Ni; Dibenzyltoluene; Catalytic activity; PERHYDRO-N-ETHYLCARBAZOLE; CATALYTIC-HYDROGENATION; DEHYDROGENATION; STORAGE; KINETICS;
D O I
10.1016/j.matpr.2020.03.232
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In recent years, Dibenzyltoluene (H0-DBT) is becoming a promising liquid organic hydrogen carrier for hydrogen storage purpose. In this study, the hydrogenation characteristics of H0-DBT were investigated under a pressure of 0.8 MPa. Initially, the catalytic activity of three different catalysts: Raney-Ni, 5% Pd/ Al2O3 and 5% Ru/Al2O3 was examined at 150 and 200 degrees C. Raney-Ni was found to be the best catalyst as compared to others. Moreover, the hydrogenation experiment was conducted over Raney-Ni catalyst to indicate the optimal temperature of the reaction. The results elucidated that 170 degrees C was the optimal reaction temperature which yielded the hydrogen capacity of 1.33 wt%. (c) 2021 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials Research - 2019.
引用
收藏
页码:1123 / 1127
页数:5
相关论文
共 50 条
  • [41] Hydrogenation of aromatic and heteroaromatic compounds - a key process for future logistics of green hydrogen using liquid organic hydrogen carrier systems
    Jorschick, H.
    Preuster, P.
    Boesmann, A.
    Wasserscheid, P.
    SUSTAINABLE ENERGY & FUELS, 2021, 5 (05) : 1311 - 1346
  • [42] Recent Advances in Homogeneous/Heterogeneous Catalytic Hydrogenation and Dehydrogenation for Potential Liquid Organic Hydrogen Carrier (LOHC) Systems
    Cho, Jun-Young
    Kim, Hahyeon
    Oh, Jeong-Eun
    Park, Boyoung Y.
    CATALYSTS, 2021, 11 (12)
  • [43] Effect of the degree of hydrogenation on the viscosity, surface tension, and density of the liquid organic hydrogen carrier system based on diphenylmethane
    Schmidt, Patrick S.
    Kerscher, Manuel
    Klein, Tobias
    Jander, Julius H.
    Bioucas, Francisco E. Berger
    Ruede, Timo
    Li, Shao
    Stadelmaier, Monika
    Hanyon, Samantha
    Fathalla, Ramy R.
    Boesmann, Andreas
    Preuster, Patrick
    Wasserscheid, Peter
    Koller, Thomas M.
    Rausch, Michael H.
    Froeba, Andreas P.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (09) : 6111 - 6130
  • [44] A new insight into the kinetics of dibenzyltoluene hydrogenation over ruthenium catalyst for hydrogen storage
    Zhao, Shidong
    Zhang, Yixuan
    Ren, Guozeng
    Wei, Huijie
    Ju, Xinfeng
    Ding, Qiuyue
    Xi, Yanyan
    Shang, Hongyan
    Ma, Lishuang
    Lin, Xufeng
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2024, 137 (03) : 1683 - 1699
  • [45] Autothermal hydrogen release from liquid organic hydrogen carrier systems
    Siegert, Fabian
    Gundermann, Michael
    Maurer, Lukas
    Hahn, Simon
    Hofmann, Jonas
    Distel, Max
    Schuehle, Johannes
    Mueller, Karsten
    Wolf, Moritz
    Preuster, Patrick
    Auer, Franziska
    Geisselbrecht, Michael
    Wasserscheid, Peter
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 91 : 834 - 842
  • [46] Charging a Liquid Organic Hydrogen Carrier with Wet Hydrogen from Electrolysis
    Jorschick, Holger
    Bulgarin, Alexander
    Alletsee, Lukas
    Preuster, Patrick
    Boesmann, Andreas
    Wasserscheid, Peter
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (04) : 4186 - +
  • [47] Dynamic power supply by hydrogen bound to a liquid organic hydrogen carrier
    Fikrt, Andre
    Brehmer, Richard
    Milella, Vito-Oronzo
    Mueller, Karsten
    Boesmann, Andreas
    Preuster, Patrick
    Alt, Nicolas
    Schluecker, Eberhard
    Wasserscheid, Peter
    Arlt, Wolfgang
    APPLIED ENERGY, 2017, 194 : 1 - 8
  • [48] Chemical utilization of hydrogen from fluctuating energy sources - Catalytic transfer hydrogenation from charged Liquid Organic Hydrogen Carrier systems
    Geburtig, Denise
    Preuster, Patrick
    Boesmann, Andreas
    Mueller, Karsten
    Wasserscheid, Peter
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (02) : 1010 - 1017
  • [49] Liquid Organic Hydrogen Carriers: Hydrogenation Thermodynamics of Aromatic Esters
    Verevkin, Sergey P.
    Samarov, Artemiy A.
    Vostrikov, Sergey V.
    Rakhmanin, Oleg S.
    HYDROGEN, 2024, 5 (03): : 644 - 668
  • [50] Hydrogenation of CaCO3 for Methane by a Liquid Organic Hydrogen Carrier in the Presence of the Catalyst Precursor NiCO3
    Shen, Tao
    Wu, Jiawen
    Liu, Qingya
    Liu, Zhenyu
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (27) : 10721 - 10728