Investigation of hydrogenation of Dibenzyltoluene as liquid organic hydrogen carrier

被引:25
|
作者
Ali, Ahsan [1 ]
Kumar, G. Udaya [1 ]
Lee, Hee Joon [1 ]
机构
[1] Kookmin Univ, Dept Mech Engn, Seoul 02707, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Liquid organic hydrogen storage; Raney-Ni; Dibenzyltoluene; Catalytic activity; PERHYDRO-N-ETHYLCARBAZOLE; CATALYTIC-HYDROGENATION; DEHYDROGENATION; STORAGE; KINETICS;
D O I
10.1016/j.matpr.2020.03.232
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In recent years, Dibenzyltoluene (H0-DBT) is becoming a promising liquid organic hydrogen carrier for hydrogen storage purpose. In this study, the hydrogenation characteristics of H0-DBT were investigated under a pressure of 0.8 MPa. Initially, the catalytic activity of three different catalysts: Raney-Ni, 5% Pd/ Al2O3 and 5% Ru/Al2O3 was examined at 150 and 200 degrees C. Raney-Ni was found to be the best catalyst as compared to others. Moreover, the hydrogenation experiment was conducted over Raney-Ni catalyst to indicate the optimal temperature of the reaction. The results elucidated that 170 degrees C was the optimal reaction temperature which yielded the hydrogen capacity of 1.33 wt%. (c) 2021 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials Research - 2019.
引用
收藏
页码:1123 / 1127
页数:5
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