Isomer of linker for NU-1000 yields a new she-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

被引：29

作者：

Lu, Zhiyong ^{[1
,2
]}

Wang, Rui ^{[2
]}

Liao, Yijun ^{[2
]}

Farha, Omar K. ^{[2
]}

Bi, Wentuan ^{[2
,3
]}

Sheridan, Thomas R. ^{[2
]}

Zhang, Kun ^{[2
,4
]}

Duan, Jiaxin ^{[2
]}

Liu, Jian ^{[2
]}

Hupp, Joseph T. ^{[2
]}

机构：

[1] Hohai Univ, Coll Mech & Mat, Nanjing 210098, Peoples R China

[2] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[4] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 29期

基金：

中国国家自然科学基金;

关键词：

HYDROLYSIS; UIO-66;

D O I：

10.1039/d0cc07974j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy(4-)) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy(4-) to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous, she-type MOF Zr-6(mu(3)-O)(4)(mu(3)-OH)(4)(C6H5COO)(3)(COO)(3)(TBAPy-2)(3/2) (NU-601), where TBAPy-2(4-) is the 4,5,9,10 isomer of TBAPy(4-). NU-601 shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

引用

页码：3571 / 3574

页数：4

共 28 条

[1] Revisiting the structural homogeneity of NU-1000, a Zr-based metal-organic framework
Islamoglu, Timur
Otake, Ken-ichi
Li, Peng
Buru, Cassandra T.
Peters, Aaron W.
Akpinar, Isil
Garibay, Sergio J.
Farha, Omar K.
CRYSTENGCOMM, 2018, 20 (39): : 5913 - 5918
[2] Computational Linker Design for Highly Crystalline Metal-Organic Framework NU-1000
Liu, Wei-Guang
Truhlar, Donald G.
CHEMISTRY OF MATERIALS, 2017, 29 (19) : 8073 - 8081
[3] Catalysis with metal clusters anchored at the Zr6-based metal-organic framework NU-1000
Gagliardi, Laura
Truhlar, Donald
Cramer, Christopher
Borycz, Joshua
Fernandez, Laura
Tussupbayev, Samat
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
[4] Defining the Proton Topology of the Zr6-Based Metal-Organic Framework NU-1000
Planas, Nora
Mondloch, Joseph E.
Tussupbayev, Samat
Borycz, Joshua
Gagliardi, Laura
Hupp, Joseph T.
Farha, Omar K.
Cramer, Christopher J.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (21): : 3716 - 3723
[5] Insights into Catalytic Hydrolysis of Organophosphate Warfare Agents by Metal-Organic Framework NU-1000
Chen, Haoyuan
Liao, Peilin
Mendonca, Matthew L.
Snurr, Randall Q.
JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (23): : 12362 - 12368
[6] Exploring catalytic hydrolysis of organophosphorus nerve agents and their simulants by the metal-organic framework NU-1000
Mendonca, Matthew
Chen, Haoyuan
Liao, Peilin
Snurr, Randall
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[7] Polypyrrole merged zirconium-based metal-organic framework NU-1000 for detection of levodopa
Biswas, Sudip
Chen, Yuling
Xie, Yao
Sun, Xin
Wang, Yang
MICROCHIMICA ACTA, 2020, 187 (12)
[8] Direct phoxim sensing based on fluorescent metal-organic framework of Nu-1000 induced FRET
Hao, Wenhui
Huang, Gengli
Jiang, Guoyong
Dauda, Sa-adu Abiola
Pi, Fuwei
FOOD BIOSCIENCE, 2023, 55
[9] Polypyrrole merged zirconium-based metal-organic framework NU-1000 for detection of levodopa
Sudip Biswas
Yuling Chen
Yao Xie
Xin Sun
Yang Wang
Microchimica Acta, 2020, 187
[10] A mesoporous Zr-based metal-organic framework driven by the assembly of an octatopic linker
Ortin-Rubio, Borja
Perona-Bermejo, Cristina
Suarez del Pino, Jose A.
Carmona, Francisco J. J.
Gandara, Felipe
Navarro, Jorge A. R.
Juanhuix, Judith
Imaz, Inhar
Maspoch, Daniel
CHEMICAL COMMUNICATIONS, 2023, 59 (50) : 7803 - 7806

← 1 2 3 →