Isomer of linker for NU-1000 yields a new she-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

被引：29

作者：

Lu, Zhiyong ^{[1
,2
]}

Wang, Rui ^{[2
]}

Liao, Yijun ^{[2
]}

Farha, Omar K. ^{[2
]}

Bi, Wentuan ^{[2
,3
]}

Sheridan, Thomas R. ^{[2
]}

Zhang, Kun ^{[2
,4
]}

Duan, Jiaxin ^{[2
]}

Liu, Jian ^{[2
]}

Hupp, Joseph T. ^{[2
]}

机构：

[1] Hohai Univ, Coll Mech & Mat, Nanjing 210098, Peoples R China

[2] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[4] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 29期

基金：

中国国家自然科学基金;

关键词：

HYDROLYSIS; UIO-66;

D O I：

10.1039/d0cc07974j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy(4-)) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy(4-) to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous, she-type MOF Zr-6(mu(3)-O)(4)(mu(3)-OH)(4)(C6H5COO)(3)(COO)(3)(TBAPy-2)(3/2) (NU-601), where TBAPy-2(4-) is the 4,5,9,10 isomer of TBAPy(4-). NU-601 shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

引用

页码：3571 / 3574

页数：4

共 28 条

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