A mesoporous Zr-based metal-organic framework driven by the assembly of an octatopic linker

被引：7
|
作者：
Ortin-Rubio, Borja [1 ,2 ,3 ]
Perona-Bermejo, Cristina [4 ]
Suarez del Pino, Jose A. [1 ,2 ,3 ]
Carmona, Francisco J. J. [4 ]
Gandara, Felipe [5 ]
Navarro, Jorge A. R. [4 ]
Juanhuix, Judith [6 ]
Imaz, Inhar [1 ,2 ,3 ]
Maspoch, Daniel [1 ,2 ,3 ,7 ]
机构：
[1] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Barcelona 08193, Spain
[2] Barcelona Inst Sci & Technol, Campus UAB, Barcelona 08193, Spain
[3] Univ Autonoma Barcelona, Dept Quim, Fac Ciencies, Bellaterra 08193, Spain
[4] Univ Granada, Dept Quim Inorgan, Ave Fuentenueva S-N, Granada 18071, Spain
[5] CSIC, Mat Sci Inst Madrid ICMM, Calle Sor Juana de la Ines Cruz 3, Madrid 28049, Spain
[6] ALBA Synchrotron, Cerdanyola Del Valles 08290, Barcelona, Spain
[7] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 50期
基金：
欧洲研究理事会;
关键词：
RETICULAR CHEMISTRY; CRYSTAL-STRUCTURES; ADSORPTION; CONSTRUCTION; DATABASE; DESIGN; NET; MOF;
D O I：
10.1039/d3cc01831h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds.
引用
收藏
页码：7803 / 7806
页数：4
相关论文
共 50 条
  • [1] Tuning the ion conductivity of Zr-based metal-organic framework ionogels by linker functionalization
    Ferbezar, Antonija
    Zettl, Roman
    Hogrefe, Katharina
    Fitzek, Harald
    Gadermaier, Bernhard
    Wilkening, H. Martin R.
    Hanzu, Ilie
    JOURNAL OF MATERIALS CHEMISTRY A, 2024, 12 (21) : 12552 - 12563
  • [2] Twinning in Zr-Based Metal-Organic Framework Crystals
    Oien-Odegaard, Sigurd
    Lillerud, Karl Petter
    CHEMISTRY-SWITZERLAND, 2020, 2 (03): : 777 - 786
  • [3] Zr-Based Metal-Organic Framework Nanocrystals for Water Remediation
    Jrad, Asmaa
    Damacet, Patrick
    Yaghi, Zahraa
    Ahmad, Mohammad
    Hmadeh, Mohamad
    ACS APPLIED NANO MATERIALS, 2022, 5 (08) : 10795 - 10808
  • [4] Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal-organic framework
    Rangwani, Sean
    Howarth, Ashlee J.
    DeStefano, Matthew R.
    Malliakas, Christos D.
    Platero-Prats, Ana E.
    Chapman, Karena W.
    Farha, Omar K.
    POLYHEDRON, 2018, 151 : 338 - 343
  • [5] Exploitation of missing linker in Zr-based metal-organic framework as the catalyst support for selective oxidation of benzyl alcohol
    Jumpathong, Watthanachai
    Pila, Taweesak
    Lekjing, Yuwanda
    Chirawatkul, Prae
    Boekfa, Bundet
    Horike, Satoshi
    Kongpatpanich, Kanokwan
    APL MATERIALS, 2019, 7 (11)
  • [6] Thermally activated delayed fluorescence of a Zr-based metal-organic framework
    Mieno, H.
    Kabe, R.
    Allendorf, M. D.
    Adachi, C.
    CHEMICAL COMMUNICATIONS, 2018, 54 (06) : 631 - 634
  • [7] Tuning the Endocytosis Mechanism of Zr-Based Metal-Organic Frameworks through Linker Functionalization
    Orellana-Tavra, Claudia
    Haddad, Salame
    Marshall, Ross J.
    Lazaro, Isabel Abanades
    Boix, Gerard
    Imaz, Inhar
    Maspoch, Daniel
    Forgan, Ross S.
    Fairen-Jimenez, David
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (41) : 35516 - 35525
  • [8] Bandgap Modulation in Zr-Based Metal-Organic Frameworks by Mixed-Linker Approach
    Cedeno, Rushie Mae
    Cedeno, Ruel
    Gapol, Maebienne Anjelica
    Lerdwiriyanupap, Tharit
    Impeng, Sarawoot
    Flood, Adrian
    Bureekaew, Sareeya
    INORGANIC CHEMISTRY, 2021, 60 (12) : 8908 - 8916
  • [9] Squeezing the box: isoreticular contraction of pyrene-based linker in a Zr-based metal-organic framework for Xe/Kr separation
    Maldonado, Rodrigo R.
    Zhang, Xuan
    Hanna, Sylvia
    Gong, Xinyi
    Gianneschi, Nathan C.
    Hupp, Joseph T.
    Farha, Omar K.
    DALTON TRANSACTIONS, 2020, 49 (20) : 6553 - 6556
  • [10] Binding of uranyl cations to a Zr-based metal-organic framework by density functional theory
    Liu, Yuan
    Ta, An T.
    Pandey, Shubham
    Park, Kyoung Chul
    Hu, Shenyang
    Shustova, Natalia B.
    Phillpot, Simon R.
    COMPUTATIONAL MATERIALS SCIENCE, 2023, 230
12345