Photopatterning of discotic liquid-crystalline gels

被引：30
|
作者：
Moriyama, M [1 ]
Mizoshita, N [1 ]
Kato, T [1 ]
机构：
[1] Univ Tokyo, Dept Chem & Biochem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
来源：
POLYMER JOURNAL | 2004年 / 36卷 / 08期
关键词：
liquid-crystalline gel; discotic liquid crystal; azobenzene; photoisomerization; photopatterning;
D O I：
10.1295/polymj.36.661
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The photopatterning and photoinduced structural changes of liquid crystalline gels materials consisting of discotic columnar liquid crystals such as 2,3,6,7,10,11-hyxahexyloxy-triphenylene (1) and photoresponsive hydrogen bonded gelator (2) were studied. The discotic liquid crystal (1) was synthesized by etherification of 2,3,6,7,10,11-hexahydroxytriphenylene and 1-bromohexane. The synthesized compound was found to exhibit a hexagonal columnar liquid crystalline (Col) phase between 69 and 100°C on heating. It was also found that the photopatterned structures of the nematic and chiral nematic gels are fixed by the aggregates of gelators.
引用
收藏
页码：661 / 664
页数：4
相关论文
共 50 条
  • [41] High Charge Mobility in Discotic Liquid-Crystalline Triindoles: Just a Core Business?
    Garcia-Frutos, Eva M.
    Pandey, Upendra K.
    Termine, Roberto
    Omenat, Ana
    Barbera, Joaquin
    Serrano, Jose L.
    Golemme, Attilio
    Gomez-Lor, Berta
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) : 7399 - 7402
  • [42] One-dimensional hopping transport in a columnar discotic liquid-crystalline glass
    Bleyl, I
    Erdelen, C
    Schmidt, HW
    Haarer, D
    PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1999, 79 (03): : 463 - 475
  • [43] A MEAN FIELD MODEL FOR THE PHASE-DIAGRAM OF A DISCOTIC LIQUID-CRYSTALLINE SYSTEM
    GHOSE, D
    BOSE, TR
    ROY, MK
    SAHA, M
    MUKHERJEE, CD
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 154 : 119 - 125
  • [44] Highly twisting enantiomeric radial multiyne dopants for discotic liquid-crystalline systems
    Booth, CJ
    Kruerke, D
    Heppke, G
    JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (06) : 927 - 934
  • [45] Photoinduced bending and unbending behavior of liquid-crystalline gels and elastomers
    Yu, YL
    Nakano, M
    Ikeda, T
    PURE AND APPLIED CHEMISTRY, 2004, 76 (7-8) : 1467 - 1477
  • [46] Nano-silica enhanced liquid-crystalline composite gels
    Li Q.
    Bi S.
    Zhao D.
    Liao Y.
    Xie X.
    Kexue Tongbao/Chin. Sc. Bull., 19 (2155-2162): : 2155 - 2162
  • [47] LIQUID-CRYSTALLINE POLYMER GELS .4. PHOTOCONTROL OF DYE ORIENTATION IN A POLYMER GEL HAVING A CHOLESTERIC LIQUID-CRYSTALLINE ORDER
    KISHI, R
    SISIDO, M
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1991, 192 (11): : 2723 - 2732
  • [48] High electron mobility in room-temperature discotic liquid-crystalline perylene diimides
    An, ZS
    Yu, JS
    Jones, SC
    Barlow, S
    Yoo, S
    Domercq, B
    Prins, P
    Siebbeles, LDA
    Kippelen, B
    Marder, SR
    ADVANCED MATERIALS, 2005, 17 (21) : 2580 - +
  • [49] Effects of side-chain flexibility on properties of azatriphenylene discotic liquid-crystalline ionomers
    Yang, Qian
    Xiong, Xiao-Ping
    Yan, Chao-Min
    Li, Long
    Chen, Hong-Mei
    Ni, Hai-Liang
    Feng, Chun
    Zhao, Ke-Qing
    Hu, Ping
    Ma, Yu-Jie
    Yu, Wen-Hao
    European Polymer Journal, 2025, 224
  • [50] Discotic liquid crystalline semiconductors
    Ohta, K
    Hatsusaka, K
    Sugibayashi, M
    Ariyoshi, M
    Ban, K
    Maeda, F
    Naito, R
    Nishizawa, K
    van de Craats, AM
    Warman, JM
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2003, 397 : 325 - 345
12345