Catalytic [2+1] cycloaddition of diazo compounds to [60]fullerene

被引：31
|
作者：
Tuktarov, A. R. [1 ]
Akhmetov, A. R. [1 ]
Sabirov, D. Sh. [1 ]
Khalilov, L. M. [1 ]
Ibragimov, A. G. [1 ]
Dzhemilev, U. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
metal complex catalysis; 60]fullerene; diazo compounds; 2+1] cycloaddition; FULLERENE; C-60; INHIBITORS; PROTEASE; BINDING;
D O I：
10.1007/s11172-009-0238-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A catalytic method for the efficient synthesis of 5,6-open and 6,6-closed (2 pi+1 pi) fullerene adducts by [2+1] cycloaddition of ethyl 2-alkyl(hetaryl)-2-diazoacetates to [60]fullerene in the presence of a three-component catalyst Pd(acac)(2)-PPh3-Et3Al have been developed.
引用
收藏
页码：1724 / 1730
页数：7
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