Catalytic [2+1] cycloaddition of diazo compounds to [60]fullerene

被引：31
|
作者：
Tuktarov, A. R. [1 ]
Akhmetov, A. R. [1 ]
Sabirov, D. Sh. [1 ]
Khalilov, L. M. [1 ]
Ibragimov, A. G. [1 ]
Dzhemilev, U. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
metal complex catalysis; 60]fullerene; diazo compounds; 2+1] cycloaddition; FULLERENE; C-60; INHIBITORS; PROTEASE; BINDING;
D O I：
10.1007/s11172-009-0238-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A catalytic method for the efficient synthesis of 5,6-open and 6,6-closed (2 pi+1 pi) fullerene adducts by [2+1] cycloaddition of ethyl 2-alkyl(hetaryl)-2-diazoacetates to [60]fullerene in the presence of a three-component catalyst Pd(acac)(2)-PPh3-Et3Al have been developed.
引用
收藏
页码：1724 / 1730
页数：7
相关论文
共 50 条
  • [31] The reaction of [60]fullerene with 2-diazo-4,5-dicyanoimidazole
    Rasmussen, PG
    Fabre, TS
    Beck, PA
    Eissa, MJ
    Escobedo, J
    Strongin, RM
    TETRAHEDRON LETTERS, 2001, 42 (39) : 6823 - 6825
  • [32] Cycloaddition of nitrile oxides to [60]fullerene
    DaRos, T
    Prato, M
    Novello, F
    Maggini, M
    DeAmici, M
    De Micheli, C
    CHEMICAL COMMUNICATIONS, 1997, (01) : 59 - 60
  • [33] Cycloaddition of tetracyanoethene oxide with [60]fullerene
    Jagerovic, N
    Elguero, J
    Aubagnac, JL
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (06): : 499 - 499
  • [34] CYCLOADDITION OF DIAZO COMPOUNDS TO ETHYLENEBORONIC AND ACETYLENEBORONIO ESTERS
    MATTESON, DS
    JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (12): : 4293 - &
  • [35] [60]Fullerene cycloaddition across hindered acenes
    Kaur, Irvinder
    Miller, Glen P.
    NEW JOURNAL OF CHEMISTRY, 2008, 32 (03) : 459 - 463
  • [36] Cycloaddition of [60]fullerene to stable benzenedicarbonitrile oxides
    V. N. Knyazev
    N. M. Przheval'skii
    G. P. Tokmakov
    A. G. Buyanovskaya
    Russian Chemical Bulletin, 1999, 48 : 218 - 219
  • [37] [2+3] cycloaddition to [60]fullerene: Advancement and future prospects
    Zhu, YL
    Cao, L
    Yin, QF
    Zhu, DB
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (02) : 159 - 166
  • [38] Cycloaddition of [60]fullerene to stable benzenedicarbonitrile oxides
    Knyazev, VN
    Przheval'skii, NM
    Tokmakov, GP
    Buyanovskaya, AG
    RUSSIAN CHEMICAL BULLETIN, 1999, 48 (01) : 218 - 219
  • [39] Catalytic interaction of 1,3-diheteracycloalkanes with diazo compounds
    Sultanova, Rimma M.
    Khanova, Marina D.
    Dokichev, Vladimir A.
    ARKIVOC, 2009, : 236 - 247
  • [40] Theoretical insights into enantioselective [2+1] cyclopropanation reactions of diazo compounds with electron-deficient olefins
    Liu, Xudong
    Zhu, Ruyu
    Yang, Yongsheng
    Xue, Ying
    Xu, Dingguo
    JOURNAL OF MOLECULAR MODELING, 2024, 30 (08)
12345