Isolation of a Small Carbon Nanotube: The Surprising Appearance of D5h(1)-C90

被引:74
|
作者
Yang, Hua [1 ]
Beavers, Christine M. [3 ]
Wang, Zhimin [1 ]
Jiang, An [1 ]
Liu, Ziyang [1 ]
Jin, Hongxiao [4 ]
Mercado, Brandon Q. [2 ]
Olmstead, Marilyn M. [2 ]
Balch, Alan L. [2 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
[4] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
carbon nanotubes; fullerenes; samarium; X-ray diffraction; CRYSTALLOGRAPHIC CHARACTERIZATION; STRUCTURE ELUCIDATION; ELECTRONIC-STRUCTURE; STABLE ISOMERS; FULLERENES; C-60; TEMPERATURE;
D O I
10.1002/anie.200906023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Totally tubular: The previously undetected higher fullerene D 5h(1)-C90 (see structure) was isolated as the major C 90 isomer produced from Sm2O3-doped graphite rods and identified structurally by X-ray crystallography. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:886 / 890
页数:5
相关论文
共 50 条
  • [41] Modelling of the stabilization of the complex of a single walled (5,5) carbon nanotube C60H20 with cumulenic or acetylenic chain
    Dinadayalane, TC
    Gorb, L
    Dodziuk, H
    Leszczynski, J
    ELECTRONIC PROPERTIES OF NOVEL NANOSTRUCTURES, 2005, 786 : 436 - 439
  • [42] Exploring the Threshold between Fullerenes and Nanotubes: Characterizing Isomerically Pure, Empty-Caged, and Tubular Fullerenes D5h-C90 and D5d-C100
    Schuesslbauer, Christoph M.
    Krug, Marcel
    Ullrich, Tobias
    Franklin, Hannah M.
    Stevenson, Steven
    Clark, Timothy
    Guldi, Dirk M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (24) : 10825 - 10829
  • [43] C50(D5h)衍生物-异质富勒烯C48P2的分子行为理论研究
    许秀芳
    尚贞锋
    李瑞芳
    赵学庄
    高等学校化学学报, 2009, 30 (06) : 1219 - 1226
  • [44] D5h C50X10:: Saturn-like fullerene derivatives (X=F, Cl, Br) -: art. no. 094305
    Chang, YF
    Zhang, JP
    Hong, B
    Sun, H
    An, Z
    Wang, RS
    JOURNAL OF CHEMICAL PHYSICS, 2005, 123 (09):
  • [45] Isolation and structural characterization of a family of endohedral fullerenes including the large, chiral cage fullerenes Tb3N@C88 and Tb3N@C86 as well as the Ih and D5h isomers of Tb3N@C80
    Zuo, Tianming
    Beavers, Christine M.
    Duchamp, James C.
    Campbell, Anne
    Dorn, Harry C.
    Olmstead, Marilyn M.
    Balch, Alan L.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) : 2035 - 2043
  • [46] Structure and enhanced reactivity rates of the D5h Sc3N@C80 and Lu3N@ C80 metallofullerene isomers:: The importance of the pyracylene motif
    Cai, Ting
    Xu, Liaosa
    Anderson, Mark R.
    Ge, Zhongxin
    Zuo, Tianming
    Wang, Xuelei
    Olmstead, Marilyn M.
    Balch, Alan L.
    Gibson, Harry W.
    Dorn, Harry C.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) : 8581 - 8589
  • [47] PYROLYSIS REACTIONS OF 1,5-C2B3H5 AND 1,6-C2B4H6 - ISOLATION OF A NEW 4-CARBON CARBORANE, C4B7H11, AND THE BORON CARBON-BONDED DIMER AND TRIMERS OF 1,5-C2B3H5 - IMPROVED SYNTHESIS OF THE MIXED-CAGE CARBORANE 2'-2-[1',5'-C2B3H4][1,6-C2B4H5]
    ASTHEIMER, RJ
    SNEDDON, LG
    INORGANIC CHEMISTRY, 1983, 22 (13) : 1928 - 1934
  • [48] CARBON- AND OXYGEN-COORDINATED CARBON MONOXIDE . FE2(PI-C5H5)2(CO)2(COA1(C2H5)3)2 AND FE4(PI-C5H5)4(COA1(C2H5)3)4
    NELSON, NJ
    KIME, NE
    SHRIVER, DF
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (18) : 5173 - &
  • [49] Synthesis and Characterization of the D5h Isomer of the Endohedral Dimetallofullerene Ce2@C80: Two-Dimensional Circulation of Encapsulated Metal Atoms Inside a Fullerene Cage
    Yamada, Michio
    Mizorogi, Naomi
    Tsuchiya, Takahiro
    Akasaka, Takeshi
    Nagase, Shigeru
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (37) : 9486 - 9493
  • [50] APPEARANCE OF DEFECT LUMINESCENCE WITH A D1 SPECTRUM DUE TO GENERATION OF EXCESS CARBON VACANCIES IN 6H-SIC
    VODAKOV, YA
    LOMAKINA, GA
    MOKHOV, EN
    ODING, VG
    RAMM, MG
    SOKOLOV, VI
    SOVIET PHYSICS SEMICONDUCTORS-USSR, 1986, 20 (08): : 900 - 902