Isolation of a Small Carbon Nanotube: The Surprising Appearance of D5h(1)-C90

被引:74
|
作者
Yang, Hua [1 ]
Beavers, Christine M. [3 ]
Wang, Zhimin [1 ]
Jiang, An [1 ]
Liu, Ziyang [1 ]
Jin, Hongxiao [4 ]
Mercado, Brandon Q. [2 ]
Olmstead, Marilyn M. [2 ]
Balch, Alan L. [2 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
[4] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
carbon nanotubes; fullerenes; samarium; X-ray diffraction; CRYSTALLOGRAPHIC CHARACTERIZATION; STRUCTURE ELUCIDATION; ELECTRONIC-STRUCTURE; STABLE ISOMERS; FULLERENES; C-60; TEMPERATURE;
D O I
10.1002/anie.200906023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Totally tubular: The previously undetected higher fullerene D 5h(1)-C90 (see structure) was isolated as the major C 90 isomer produced from Sm2O3-doped graphite rods and identified structurally by X-ray crystallography. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:886 / 890
页数:5
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