Hydrated Electrons at the Water/Air Interface

被引：79
|
作者：
Sagar, D. M. [1 ]
Bain, Colin D. [1 ]
Verlet, Jan R. R. [1 ]
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 20期
基金：
英国工程与自然科学研究理事会;
关键词：
SUM-FREQUENCY SPECTROSCOPY; EXCESS ELECTRONS; SOLVATED ELECTRONS; CLUSTER ANIONS; SURFACE; PHOTODETACHMENT; IONIZATION; SOLVENT; CHAIN; BULK;
D O I：
10.1021/ja101176r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dynamics of hydrated electrons at the water/air interface are investigated using time-resolved second-harmonic generation spectroscopy. Initial solvation occurs in 1 ps, and the electron remains at the interface for >750 ps. The location of the electron relative to the dividing surface is investigated using surfactants, which show that the electron is hydrated in the interfacial region, below the dividing surface.
引用
收藏
页码：6917 / +
页数：4
相关论文
共 50 条
  • [31] Ions at the air/water interface
    Jungwirth, P
    Tobias, DJ
    JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (25): : 6361 - 6373
  • [32] Ions at the air/water interface
    Garrett, BC
    SCIENCE, 2004, 303 (5661) : 1146 - 1147
  • [33] POLYMERS AT THE AIR/WATER INTERFACE
    REYNOLDS, I
    RICHARDS, RW
    ROCHFORD, BR
    MACROMOLECULAR SYMPOSIA, 1995, 100 : 39 - 49
  • [34] Structure of Hydrated Sodium Ions and Water Molecules Adsorbed on the Mica/Water Interface
    Sakuma, Hiroshi
    Kondo, Toshihiro
    Nakao, Hironori
    Shiraki, Koichi
    Kawamura, Katsuyuki
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (32): : 15959 - 15964
  • [35] Interconversion of hydrated protons at the interface between liquid water and platinum
    Rice, Peter S.
    Mao, Yu
    Guo, Chenxi
    Hu, P.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (11) : 5932 - 5940
  • [36] HYDRATED ELECTRONS AND RADIOBIOLOGICAL SENSITISATION
    ADAMS, GE
    DEWEY, DL
    BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1963, 12 (06) : 473 - +
  • [37] THE TURBULENT LAYER IN THE WATER AT AN AIR WATER INTERFACE
    CHEUNG, TK
    STREET, RL
    JOURNAL OF FLUID MECHANICS, 1988, 194 : 133 - 151
  • [38] HYDRATED ELECTRONS AND PREBIOTIC EVOLUTION
    SCOTT, JE
    JOURNAL OF THEORETICAL BIOLOGY, 1979, 81 (01) : 19 - 27
  • [39] HYDRATED ELECTRONS PROBED EXPERIMENTALLY
    不详
    CHEMICAL & ENGINEERING NEWS, 2010, 88 (10) : 36 - 36
  • [40] ELECTROCHEMICALLY GENERATED HYDRATED ELECTRONS
    BEWICK, A
    CONWAY, BE
    TUXFORD, AM
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 42 (01): : A11 - A15
12345