Hydrated Electrons at the Water/Air Interface

被引：79

作者：

Sagar, D. M. ^{[1
]}

Bain, Colin D. ^{[1
]}

Verlet, Jan R. R. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

SUM-FREQUENCY SPECTROSCOPY; EXCESS ELECTRONS; SOLVATED ELECTRONS; CLUSTER ANIONS; SURFACE; PHOTODETACHMENT; IONIZATION; SOLVENT; CHAIN; BULK;

D O I：

10.1021/ja101176r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dynamics of hydrated electrons at the water/air interface are investigated using time-resolved second-harmonic generation spectroscopy. Initial solvation occurs in 1 ps, and the electron remains at the interface for >750 ps. The location of the electron relative to the dividing surface is investigated using surfactants, which show that the electron is hydrated in the interfacial region, below the dividing surface.

引用

页码：6917 / +

页数：4

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