Bis[tris(1,10-phenanthroline-κ2 N,N)′ manganese(II)] dodecatungstogermanate dihydrate

被引:2
|
作者
Zhou, Da-Peng [1 ]
Guo, Gui-Ling [1 ]
机构
[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475001, Henan, Peoples R China
关键词
D O I
10.1107/S1600536807012196
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Mn(C12H8N2)(3)](2)[GeW12O40](.)2H(2)O, which was prepared under hydrothermal conditions, consists of one Keggin [GeW12O40](4-) anion disordered over an inversion centre, two isolated [Mn(phen)(3)](2+) cations (phen is 1,10-phenanthroline) and two solvent water molecules. In each [Mn(phen)(3)](2+) cation, the Mn-II ion is coordinated by six N atoms from three phen ligands, completing a distorted octahedral geometry.
引用
收藏
页码:M1122 / M1124
页数:3
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