Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

被引：5
|
作者：
Delmas, Luke C. [1 ]
White, Andrew J. P. [1 ]
Pugh, David [1 ]
Horton, Peter N. [2 ]
Coles, Simon J. [2 ]
Lickiss, Paul D. [1 ]
Davies, Robert P. [1 ]
机构：
[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England
[2] Univ Southampton, Dept Chem, EPSRC Crystallog Serv, Southampton SO17 1BJ, Hants, England
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 32期
基金：
英国工程与自然科学研究理事会;
关键词：
CRYSTAL-STRUCTURE; PERMANENT POROSITY; ACID; CONSTRUCTION; TRINUCLEAR; MOLECULES; CHEMISTRY; NETWORK; DESIGN; MOTIF;
D O I：
10.1039/c8ce00662h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hexacarboxylic acid with a trisiloxane backbone (L-H-6) has been prepared and applied in MOF construction. L-H-6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H-6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.
引用
收藏
页码：4541 / 4545
页数：5
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