Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

被引：5

作者：

Delmas, Luke C. ^{[1
]}

White, Andrew J. P. ^{[1
]}

Pugh, David ^{[1
]}

Horton, Peter N. ^{[2
]}

Coles, Simon J. ^{[2
]}

Lickiss, Paul D. ^{[1
]}

Davies, Robert P. ^{[1
]}

机构：

[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England

[2] Univ Southampton, Dept Chem, EPSRC Crystallog Serv, Southampton SO17 1BJ, Hants, England

来源：

CRYSTENGCOMM | 2018年 / 20卷 / 32期

基金：

英国工程与自然科学研究理事会;

关键词：

CRYSTAL-STRUCTURE; PERMANENT POROSITY; ACID; CONSTRUCTION; TRINUCLEAR; MOLECULES; CHEMISTRY; NETWORK; DESIGN; MOTIF;

D O I：

10.1039/c8ce00662h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hexacarboxylic acid with a trisiloxane backbone (L-H-6) has been prepared and applied in MOF construction. L-H-6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H-6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.

引用

页码：4541 / 4545

页数：5

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