Sputtering-assisted metal-organic chemical vapor deposition of Yb-doped ZnO for photonic conversion in Si solar cells

被引:7
|
作者
Okada, Ryutaro [1 ]
Miao, Wei [1 ]
Terai, Yoshikazu [1 ]
Tsuji, Takahiro [1 ]
Fujiwara, Yasufumi [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Div Mat & Mfg Sci, Suita, Osaka 5650871, Japan
关键词
Yb3+; ZnO; photoluminescence; CVD; THIN-FILMS; EMISSION; TM;
D O I
10.1002/pssc.201300614
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have grown Yb-doped ZnO (ZnO:Yb) on c-plane sapphire substrates by sputtering-assisted metal-organic chemical vapor deposition (SA-MOCVD). X-ray diffraction (XRD) revealed that these ZnO:Yb films exhibit a c-axis orientation and that the lattice constant increases with Yb concentration. After annealing the samples at 600 degrees C for 0.5 h in O2, they showed a clear 980 nm emission due to the intra-4f shell transitions of F-2(5/2) -F-2(7/2) in Yb3+ ions. It turns out that Yb lu-minescent centers with different local structures coexist, which exhibit different energy transfer processes from the ZnO host. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
引用
收藏
页码:1292 / 1295
页数:4
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