Nonlinear Optical Properties of Polyynes: An Experimental Prediction for Carbyne

被引：31
|
作者：
Agarwal, Nisha R. [1 ,5 ]
Lucotti, Andrea [1 ]
Tommasini, Matteo [1 ]
Chalifoux, Wesley A. [2 ]
Tykwinski, Rik R. [3 ,4 ]
机构：
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy
[2] Univ Nevada, Dept Chem, Reno, NV 89557 USA
[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany
[4] Univ Erlangen Nurnberg, ICMM, Henkestr 42, D-91054 Erlangen, Germany
[5] Chalmers Univ Technol, S-41296 Gothenburg, Sweden
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 20期
基金：
加拿大自然科学与工程研究理事会;
关键词：
EFFECTIVE CONJUGATION LENGTH; RAMAN-SPECTROSCOPY; CARBON CHAINS; ORGANIC MATERIALS; CAPPED POLYYNES; LASER-ABLATION; HYPERPOLARIZABILITY; MOLECULES; OLIGOMERS; MODEL;
D O I：
10.1021/acs.jpcc.6b03071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present the experimental determination of the vibrational contribution to molecular second hyperpolarizability (gamma(vib)) of very long polyynes that have been recently made available thanks to progress in chemical synthesis. Based on a simple theoretical model, the available experimental data allow estimating the asymptotic behavior of the vibrational contribution to molecular hyperpolarizability for increasing chain length.
引用
收藏
页码：11131 / 11139
页数：9
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