Nonlinear Optical Properties of Polyynes: An Experimental Prediction for Carbyne

被引：31
|
作者：
Agarwal, Nisha R. [1 ,5 ]
Lucotti, Andrea [1 ]
Tommasini, Matteo [1 ]
Chalifoux, Wesley A. [2 ]
Tykwinski, Rik R. [3 ,4 ]
机构：
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy
[2] Univ Nevada, Dept Chem, Reno, NV 89557 USA
[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany
[4] Univ Erlangen Nurnberg, ICMM, Henkestr 42, D-91054 Erlangen, Germany
[5] Chalmers Univ Technol, S-41296 Gothenburg, Sweden
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 20期
基金：
加拿大自然科学与工程研究理事会;
关键词：
EFFECTIVE CONJUGATION LENGTH; RAMAN-SPECTROSCOPY; CARBON CHAINS; ORGANIC MATERIALS; CAPPED POLYYNES; LASER-ABLATION; HYPERPOLARIZABILITY; MOLECULES; OLIGOMERS; MODEL;
D O I：
10.1021/acs.jpcc.6b03071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present the experimental determination of the vibrational contribution to molecular second hyperpolarizability (gamma(vib)) of very long polyynes that have been recently made available thanks to progress in chemical synthesis. Based on a simple theoretical model, the available experimental data allow estimating the asymptotic behavior of the vibrational contribution to molecular hyperpolarizability for increasing chain length.
引用
收藏
页码：11131 / 11139
页数：9
相关论文
共 50 条
  • [31] MATHEMATICAL INTERPRETATION OF EXPERIMENTAL RESEARCH RESULTS ON NONLINEAR OPTICAL MATERIAL PROPERTIES
    Starkov, V. N.
    Brodyn, M. S.
    Tomchuk, P. M.
    Gayvoronsky, V. Ya
    Boyarchuk, A. Yu
    UKRAINIAN JOURNAL OF PHYSICS, 2015, 60 (07): : 601 - 613
  • [32] Nonlinear Optical Properties of Bis(dehydrobenzoannuleno)benzenes: An Experimental and Computational Approach
    Sandoval, Juan S.
    Haley, Michael M.
    Goodson, Theodore
    JOURNAL OF PHYSICAL CHEMISTRY A, 2025, 129 (05): : 1240 - 1251
  • [33] Nonlinear optical properties of chiral polyesters: A joint experimental and theoretical study
    Philip, B
    Sreekumar, K
    SMART MATERIALS, STRUCTURES, AND SYSTEM, PTS 1 AND 2, 2003, 5062 : 116 - 123
  • [34] Experimental linear and calculated nonlinear optical properties of SeTePb glassy films
    Atyia, H. E.
    Bekheet, A. E.
    PHYSICA B-CONDENSED MATTER, 2017, 517 : 19 - 24
  • [35] Size scaling of intramolecular charge transfer driven optical properties of substituted polyenes and polyynes
    Lee, JY
    Mhin, BJ
    Mukamel, S
    Kim, KS
    JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (14): : 7519 - 7524
  • [36] Prediction of the Linear and Nonlinear Optical Properties of a Schiff Base Derivatives via DFT
    Valverde, Clodoaldo
    Ribeiro, Italo Nuta
    Soares, Joao Victor B.
    Baseia, Basilio
    Osorio, Francisco A. P.
    ADVANCES IN CONDENSED MATTER PHYSICS, 2019, 2019
  • [37] Hydroxyflavone-containing polymers: theoretical prediction of spectral and nonlinear optical properties
    Mishurov, D.
    Voronkin, A.
    Roshal, A.
    FUNCTIONAL MATERIALS, 2019, 26 (01): : 164 - 173
  • [38] Hyperbranched polyynes show novel properties
    不详
    CHEMICAL & ENGINEERING NEWS, 2004, 82 (29) : 19 - 19
  • [39] Supermultiplexed optical imaging and barcoding with engineered polyynes
    Hu F.
    Zeng C.
    Long R.
    Miao Y.
    Wei L.
    Xu Q.
    Min W.
    Nature Methods, 2018, 15 (3) : 194 - 200
  • [40] Supermultiplexed optical imaging and barcoding with engineered polyynes
    Hu, Fanghao
    Zeng, Chen
    Long, Rong
    Miao, Yupeng
    Wei, Lu
    Xu, Qizhi
    Min, Wei
    NATURE METHODS, 2018, 15 (03) : 194 - +
12345