The mechanism of the excited-state multiple proton transfer reaction for 3-Me-2,6-diazaindole in aqueous solution

被引：15
|
作者：
Huang, Jin-Dou [2 ,3 ]
Ma, Huipeng [1 ]
机构：
[1] Dalian Med Univ, Coll Med Lab Sci, Dalian 116044, Peoples R China
[2] Dalian Nationalities Univ, Sch Phys & Mat Engn, Key Lab Photosensit Mat & Devices Liaoning Prov, Key Lab New Energy & Rare Earth Resource Utilizat, Dalian 116600, Peoples R China
[3] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 18期
基金：
美国国家科学基金会;
关键词：
HYDROGEN-BONDING CATALYSTS; ASYMMETRIC CATALYSIS; LEWIS-ACID; CYCLOADDITION; KINETICS; DONORS;
D O I：
10.1039/c8qo00628h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The optical properties of 3-Me-2,6-diazaindole in aqueous solution were simulated and then found to compare well with experimental data. Furthermore, the ground state and exited state potential energy surfaces for 3-Me-2,6-diazaindole + L3H(2)O were constructed, and a new three water molecules-assisted exited state quadruple proton transfer mechanism is proposed.
引用
收藏
页码：2749 / 2753
页数：5
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