The mechanism of the excited-state multiple proton transfer reaction for 3-Me-2,6-diazaindole in aqueous solution

被引：15

作者：

Huang, Jin-Dou ^{[2
,3
]}

Ma, Huipeng ^{[1
]}

机构：

[1] Dalian Med Univ, Coll Med Lab Sci, Dalian 116044, Peoples R China

[2] Dalian Nationalities Univ, Sch Phys & Mat Engn, Key Lab Photosensit Mat & Devices Liaoning Prov, Key Lab New Energy & Rare Earth Resource Utilizat, Dalian 116600, Peoples R China

[3] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 18期

基金：

美国国家科学基金会;

关键词：

HYDROGEN-BONDING CATALYSTS; ASYMMETRIC CATALYSIS; LEWIS-ACID; CYCLOADDITION; KINETICS; DONORS;

D O I：

10.1039/c8qo00628h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The optical properties of 3-Me-2,6-diazaindole in aqueous solution were simulated and then found to compare well with experimental data. Furthermore, the ground state and exited state potential energy surfaces for 3-Me-2,6-diazaindole + L3H(2)O were constructed, and a new three water molecules-assisted exited state quadruple proton transfer mechanism is proposed.

引用

页码：2749 / 2753

页数：5

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