A torsion study on the sublimation process of InCl3

被引：20
|
作者：
Brunetti, B [1 ]
Piacente, V [1 ]
Scardala, P [1 ]
机构：
[1] Univ Rome La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1998年 / 43卷 / 01期
关键词：
D O I：
10.1021/je970188a
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The temperature dependence of the total vapor pressure above InCl3, as measured by the torsion-effusion method, is expressed by the equation log(p/kPa) = 12.76 +/- 0.15 - (8570 +/- 200)/(T/K) in the temperature range 495 to 648 K. In addition to InCl3(g), the presence of the dimeric form In2Cl6(g) was observed in the vapor at high temperature. The sublimation process InCl3(s) = InCl3(g) was studied, and the standard enthalpy of this reaction was found to be (158 +/- 4) kJ mol(-1).
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页码：101 / 104
页数：4
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