A torsion study on the sublimation process of InCl3

被引：20
|
作者：
Brunetti, B [1 ]
Piacente, V [1 ]
Scardala, P [1 ]
机构：
[1] Univ Rome La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1998年 / 43卷 / 01期
关键词：
D O I：
10.1021/je970188a
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The temperature dependence of the total vapor pressure above InCl3, as measured by the torsion-effusion method, is expressed by the equation log(p/kPa) = 12.76 +/- 0.15 - (8570 +/- 200)/(T/K) in the temperature range 495 to 648 K. In addition to InCl3(g), the presence of the dimeric form In2Cl6(g) was observed in the vapor at high temperature. The sublimation process InCl3(s) = InCl3(g) was studied, and the standard enthalpy of this reaction was found to be (158 +/- 4) kJ mol(-1).
引用
收藏
页码：101 / 104
页数：4
相关论文
共 50 条
  • [31] RAMAN AND INFRARED-SPECTRA OF MONOMERIC INCL3 IN KRYPTON MATRICES
    GIVAN, A
    LOEWENSCHUSS, A
    JOURNAL OF MOLECULAR STRUCTURE, 1979, 55 (02) : 163 - 168
  • [32] Measurement of diffusion of InCl3 in AgCl single crystal by internal friction
    Tateno, H
    Kajihara, M
    Iwashita, Y
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (5B): : 3495 - 3500
  • [33] 高纯无水InCl3的制备工艺研究
    姜宏伟
    宋宁
    严玉环
    有色金属加工, 2008, (02) : 15 - 16+23
  • [34] Measurement of diffusion of InCl3 in AgCl single crystal by internal friction
    Tateno, Hiroto
    Kajihara, Makoto
    Iwashita, Yoichiro
    1600, Japan Society of Applied Physics (40): : 3495 - 3500
  • [35] Kinetically controlled solid state reactions in the system InCl3/Sn
    Kallmayer, V
    Beck, HP
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (05): : 1085 - 1090
  • [36] InCl3:: A mild Lewis acid but efficient reagent in organic synthesis
    Babu, SA
    SYNLETT, 2002, (03) : 531 - 532
  • [37] Atom transfer cyclization catalyzed by InCl3 via halogen activation
    Cook, GR
    Hayashi, R
    ORGANIC LETTERS, 2006, 8 (06) : 1045 - 1048
  • [38] InCl3:: A new Lewis acid catalyst for reactions with α-diazocarbonyl compounds
    Sengupta, S
    Mondal, S
    TETRAHEDRON LETTERS, 1999, 40 (49) : 8685 - 8688
  • [39] AN ORDERING TRANSITION IN INCL3 STAGE-2 INTERCALATED GRAPHITE
    DATARS, WR
    PALIDWAR, J
    UMMAT, PK
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1995, 7 (29) : 5967 - 5974
  • [40] In vivo distribution and speciation of [114mIn]InCl3 in the Wistar rat
    Van Hulle, M
    De Cremer, K
    Cornelis, R
    Lameire, N
    JOURNAL OF ENVIRONMENTAL MONITORING, 2001, 3 (01): : 86 - 90
12345