ADDUCTS OF INCL3, WITH LEWIS-BASES - CRYSTAL AND MOLECULAR-STRUCTURE OF [(INCL3)(2)(DME)(3)]

被引：11
|
作者：
CARTA, G [1 ]
BENETOLLO, F [1 ]
SITRAN, S [1 ]
ROSSETTO, G [1 ]
BRAGA, F [1 ]
ZANELLA, P [1 ]
机构：
[1] CNR, IST CHIM & TECNOL INORGAN & MAT AVANZATI, AREA RIC, I-35127 PADUA, ITALY
来源：
POLYHEDRON | 1995年 / 14卷 / 13-14期
关键词：
D O I：
10.1016/0277-5387(94)00449-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A number of adducts of InCl3 with selected Lewis bases have been synthesized and characterized. The complex of InCl3 with 1,2-dimethoxyethane (DME = CH3OCH2CH2OCH3) is characterized by two centrosymmetrically related InCl3 . DME . 0.5 DME units, where the indium is six-coordinated to three chlorine atoms, two oxygen atoms of one chelating DME unit and one oxygen atom of the bridging DME ligand in a fac-octahedral arrangement. The suitability and limits of using InCl3 . 3/2DME for the synthesis of InMe(3) (Me = CH3) are discussed.
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收藏
页码：1923 / 1928
页数：6
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