Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C5H14N2)[HgCl4]•H2O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior

被引:10
|
作者
Ayari, Chaima [1 ]
Alotaibi, Abdullah A. [2 ]
Baashen, Mohammed A. [2 ]
Alotaibi, Khalid M. [3 ]
Alharbi, Khadijah H. [4 ]
Othmani, Abdelhak [5 ]
Fujita, Wataru [6 ]
Ben Nasr, Cherif [1 ]
Mrad, Mohamed Habib [1 ,2 ]
机构
[1] Univ Carthage, Fac Sci Bizerte, Mat Chem Lab, Zarzouna 7021, Tunisia
[2] Shaqra Univ, Coll Sci & Humanities, Dept Chem, Shaqra 11911, Saudi Arabia
[3] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[4] King Abdulaziz Univ, Coll Sci & Arts, Dept Chem, Rabigh 21589, Saudi Arabia
[5] Univ Carthage, Fac Sci, Lab Mat Phys Struct & Properties, LR01ES15, Zarzouna 7021, Tunisia
[6] Tokyo Univ Marine Sci & Technol, Fac Marine Engn, Dept Marine Elect & Mech Engn, Tokyo 1358533, Japan
关键词
photoluminescence; FT-IR; chloromercurate (II); dielectric analysis; antioxidant activity; CONDUCTION MECHANISM; MODULUS SPECTROSCOPY; MAGNETIC-PROPERTIES; OPTICAL-PROPERTIES; COMPLEXES; IMPEDANCE; ELABORATION; RELAXATION; CHEMISTRY; MERCURY;
D O I
10.3390/cryst12040486
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Using acid-base assays and simple slow evaporation method at ambient temperature, we were successful in producing a novel salt with the chemical formula (C5H14N2)[HgCl4]center dot H2O. According to single-crystal X-ray diffraction data, the crystal packing was regulated by H-bonds and by Coulomb interactions (also called electrostatic interactions) between distinct entities, which formed a 3D network. The 2D fingerprint plots and the Hirshfeld surface were utilized to examine the effect of intermolecular interactions. FTIR spectroscopy, PL spectroscopy, thermal analysis, and electrical conductivity experiments were also carried out, and the antioxidant activity was tested.
引用
收藏
页数:21
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