Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C5H14N2)[HgCl4]•H2O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior

被引:10
|
作者
Ayari, Chaima [1 ]
Alotaibi, Abdullah A. [2 ]
Baashen, Mohammed A. [2 ]
Alotaibi, Khalid M. [3 ]
Alharbi, Khadijah H. [4 ]
Othmani, Abdelhak [5 ]
Fujita, Wataru [6 ]
Ben Nasr, Cherif [1 ]
Mrad, Mohamed Habib [1 ,2 ]
机构
[1] Univ Carthage, Fac Sci Bizerte, Mat Chem Lab, Zarzouna 7021, Tunisia
[2] Shaqra Univ, Coll Sci & Humanities, Dept Chem, Shaqra 11911, Saudi Arabia
[3] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[4] King Abdulaziz Univ, Coll Sci & Arts, Dept Chem, Rabigh 21589, Saudi Arabia
[5] Univ Carthage, Fac Sci, Lab Mat Phys Struct & Properties, LR01ES15, Zarzouna 7021, Tunisia
[6] Tokyo Univ Marine Sci & Technol, Fac Marine Engn, Dept Marine Elect & Mech Engn, Tokyo 1358533, Japan
关键词
photoluminescence; FT-IR; chloromercurate (II); dielectric analysis; antioxidant activity; CONDUCTION MECHANISM; MODULUS SPECTROSCOPY; MAGNETIC-PROPERTIES; OPTICAL-PROPERTIES; COMPLEXES; IMPEDANCE; ELABORATION; RELAXATION; CHEMISTRY; MERCURY;
D O I
10.3390/cryst12040486
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Using acid-base assays and simple slow evaporation method at ambient temperature, we were successful in producing a novel salt with the chemical formula (C5H14N2)[HgCl4]center dot H2O. According to single-crystal X-ray diffraction data, the crystal packing was regulated by H-bonds and by Coulomb interactions (also called electrostatic interactions) between distinct entities, which formed a 3D network. The 2D fingerprint plots and the Hirshfeld surface were utilized to examine the effect of intermolecular interactions. FTIR spectroscopy, PL spectroscopy, thermal analysis, and electrical conductivity experiments were also carried out, and the antioxidant activity was tested.
引用
收藏
页数:21
相关论文
共 50 条
  • [31] Investigation of the Crystal Structure, Characterization, Hirshfeld Surface, and Theoretical Study of (C6H14N)5[HP2Mo5O23]•4H2O
    Harchani, Ali
    Haddad, Amor
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (22): : 1744 - 1751
  • [32] Synthesis, Crystal Structure and Antitumor Activity of a New Coordination Polymer [Cd(C14H10N3O5)2(C5H5N)2]n
    Qiu Xiao-Yang
    Zhu Mei-An
    Zhang Ming-Wei
    Xu Mao-Tian
    Zhu Hai-Liang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (05) : 806 - 810
  • [33] Hydrothermal synthesis and characterization of two new three-dimensional fluoroindium phosphates In4(PO4)4(H2O)4F2 • C6H14N2 and In8(PO4)8(H2O)8F4 • (C5H14N2)2
    Yi, Z
    Yang, YL
    Huang, KK
    Li, GH
    Chen, C
    Wang, W
    Liu, YL
    Pang, WQ
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (11) : 4073 - 4080
  • [34] Synthesis,Crystal Structure and Antitumor Activity of a New Coordination Polymer [Cd(C14H10N3O5)2(C5H5N)2]n
    仇晓阳
    朱美安
    张明伟
    徐茂田
    朱海亮
    结构化学, 2010, 29 (05) : 806 - 810
  • [35] Crystal structure of 1,2-bis(4-pyridinium)ethane tetrachlorocobaltate(II) monohydrate, (C12H14N2)[CoCl4]•H2O
    Wei, DY
    Xie, HZ
    Zheng, YQ
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2005, 220 (03): : 497 - 498
  • [36] Chemical preparation, crystal structure, Hirshfeld surface analysis, spectroscopy, DFT studies, thermal decomposition and magnetic measurements of (C4H12N2)[FeCl3(H2O)3]Cl2
    Kadri, Ines
    Elleuch, Slim
    Tavares, Carlos Jose
    Banobre-Lopez, Manuel
    Francoise, Michel
    Rekik, Walid
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 112
  • [37] Synthesis, crystal structure, spectroscopic study and Hirshfeld surface analysis of [Ni(C6H8N2)3]Cl2.2(H2O) (1)
    Jbali, W.
    Selmi, W.
    Jouffret, L.
    Marzouki, R.
    Zid, M. F.
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1225
  • [38] Synthesis and Crystal Structure of a Novel Three-dimensional Cu(II) Compound{[Cu(2,2'-bipy)(C7H4O5S)(H2O)2]·H2O}n
    SU Wei CAO Rong② BI Wen-Hua LI Xing (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (04) : 403 - 406
  • [39] Synthesis and crystal structure of a novel three-dimensional Cu(II) compound {[Cu(2,2′-bipy)(C7H4O5S)(H2O)2]•H2O}n
    Su, W
    Cao, R
    Bi, WH
    Li, X
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (04) : 403 - 406
  • [40] Synthesis, Crystal Structure and Characterization of a New Dabcodiium Hexaaquacobalt(II) Bis(Selenate), (C6H14N2)[Co(H2O)6](SeO4)2
    Omar Kammoun
    Nouha Loulou
    Walid Rekik
    Houcine Naïli
    Tahar Mhiri
    Thierry Bataille
    Journal of Chemical Crystallography, 2012, 42 : 103 - 110