Microwave assisted, palladium catalyzed aminocarbonylations of heteroaromatic bromides using solid Mo(CO)6 as the carbon monoxide source

被引：38

作者：

Letavic, Michael A. ^{[1
]}

Ly, Kiev S. ^{[1
]}

机构：

[1] Johnson & Johnson Pharmaceut Res & Dev LLC, San Diego, CA 92121 USA

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 13期

关键词：

D O I：

10.1016/j.tetlet.2007.01.133

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct conversion of a variety of heteroaromatic bromides into heteroaromatic amides is described. This reaction utilizes Mo(CO)(6) as the carbon monoxide source and is performed using microwave heating allowing for very short reaction times. This convenient methodology allows for the preparation of a variety of heteroaromatic amides useful in medicinal chemistry applications. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2339 / 2343

页数：5

共 46 条

[21] Palladium-free aminocarbonylation of aryl, benzyl, and styryl iodides and bromides by amines using Mo(CO)6 and norbornadiene
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TETRAHEDRON, 2013, 69 (01) : 418 - 426
[22] Microwave-Assisted Synthesis of Weinreb and MAP Aryl Amides via Pd-Catalyzed Heck Aminocarbonylation Using Mo(CO)6 or W(CO)6
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[23] Microwave-assisted, Mo(CO)6-mediated, palladium-catalyzed amino-carbonylation of aryl halides using allylamine:: from exploration to scale-up
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TETRAHEDRON LETTERS, 2008, 49 (39) : 5625 - 5628
[24] Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Bromides Using Near Stoichiometric Carbon Monoxide (vol 16, pg 2216, 2014)
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[25] Palladium-Catalyzed Formation of N-Heteroarenes from Nitroarenes using Molybdenum Hexacarbonyl as the Source of Carbon Monoxide
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ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (16-17) : 3463 - 3468
[26] Mo(CO)6 as a Solid CO Source in the Synthesis of Aryl/Heteroaryl Weinreb Amides under Microwave-Enhanced Condition
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AUSTRALIAN JOURNAL OF CHEMISTRY, 2017, 70 (01) : 44 - 51
[27] Palladium-Catalyzed Carbamoyl-Carbamoylation/ Carboxylation/Thioesterification of Alkene-Tethered Carbamoyl Chlorides Using Mo(CO)6 as the Carbonyl Source
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ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (04) : 794 - 801
[28] PALLADIUM-CATALYZED AMINOCARBONYLATION OF NITROGEN-CONTAINING ARYL HALIDES USING [11C]BH3CO AS SOURCE OF CARBON MONOXIDE
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[29] Palladium-Catalyzed Aminocarbonylation Reaction to Access 1,3,4-Oxadiazoles using Chloroform as the Carbon Monoxide Source
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[30] Pd/C-Catalyzed Aminocarbonylation of Aryl Iodides with Anthranils in Water Using Mo(CO)6 as the CO Source
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