The Effect of Pr Doping Contents on the Structural, Microstructure and Dielectric Properties of BaBi2Nb2O9 Aurivillius Ceramics

被引:5
|
作者
Rerak, Michal [1 ]
Makowska, Jolanta [1 ]
Osinska, Katarzyna [1 ]
Goryczka, Tomasz [1 ]
Zawada, Anna [2 ]
Adamczyk-Habrajska, Malgorzata [1 ]
机构
[1] Univ Silesia, Fac Sci & Technol, 1A 75 Pulku Piechoty St, PL-41500 Chorzow, Poland
[2] Czestochowa Tech Univ, Fac Prod Engn & Mat Technol, Aleja Armii Krajowej 19 Str, PL-42200 Czestochowa, Poland
关键词
ceramics; Aurivillius structure; BaBi2Nb2O9; praseodymium Pr3+; BISMUTH OXIDE LAYERS; LEAD; BEHAVIOR; N=2;
D O I
10.3390/ma15165790
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Aurivillius BaBi2Nb2O9 and Ba1-xPrxBi2Nb2O9 ceramics were successfully synthesized by a simple solid state reaction method. Ceramics were prepared from reactants: Nb2O5, Bi2O3, BaCO3 and Pr2O3. The microstructure, structure, chemical composition, and dielectric properties of the obtained materials were examined. Dielectric properties were investigated in a wide range of temperatures (T = 20-500 degrees C) and frequencies (f = 0.1 kHz-1 MHz). The obtained ceramic materials belong to the group of layered perovskites, crystallizing in a tetragonal structure with the space group I4/mmm. Modification of the barium niobate compound with praseodymium ions influenced its dielectric properties and introducing a small concentration of the dopant ion causes a slight increase in the value of electric permittivity and shifts its maximum towards higher temperatures.
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收藏
页数:15
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