Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

被引：7
|
作者：
Kawasaki, Tsuneomi [1 ]
Kaimori, Yoshiyasu [1 ]
Shimada, Seiya [1 ]
Hara, Natsuki [1 ]
Sato, Susumu [1 ]
Suzuki, Kenta [1 ]
Asahi, Toru [2 ]
Matsumoto, Arimasa [1 ,4 ]
Soai, Kenso [1 ,3 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
[2] Waseda Univ TWIns, Dept Life Sci & Med Biosci, Shinjuku Ku, Wakamatsu Cho, Tokyo 1628480, Japan
[3] Waseda Univ, Res Org Nano & Life Innovat, Shinjuku Ku, Wasedatsurumaki Cho, Tokyo 1620041, Japan
[4] Nara Womens Univ, Dept Chem Biol & Environm Sci, Kita Uoya Nishi Machi, Nara 6308506, Japan
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 49期
基金：
日本学术振兴会;
关键词：
CIRCULARLY-POLARIZED-LIGHT; SYMMETRY-BREAKING; ENANTIOSELECTIVE SYNTHESIS; GLYCINE SULFATE; AMPLIFICATION; MOLECULES; MECHANISM; PHASE; QUANTIFICATION; HOMOCHIRALITY;
D O I：
10.1039/d1cc02162a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
引用
收藏
页码：5999 / 6002
页数：4
相关论文
共 50 条
  • [41] The switchable chirality and optical properties of hexabenzo[a,c,k,m,u,w] trinaphthylene controlled by synergistic effect of static electric field and substituents: A DFT study
    Zhang, Feng-Yi
    Han, Xing-Qi
    Zhang, Yong-Jun
    Xu, Hong-Liang
    Su, Zhong-Min
    DYES AND PIGMENTS, 2024, 223
  • [42] Linear and nonlinear optical properties in an asymmetric double quantum well under intense laser field: Effects of applied electric and magnetic fields
    Yesilgul, U.
    Al, E. B.
    Martinez-Orozco, J. C.
    Restrepo, R. L.
    Mora-Ramos, M. E.
    Duque, C. A.
    Ungan, F.
    Kasapoglu, E.
    OPTICAL MATERIALS, 2016, 58 : 107 - 112
  • [43] Symmetric and asymmetric GaAs/Al0.3Ga0.7As double quantum well subjected to hydrostatic pressure and applied electric field
    Morales, AL
    Raigoza, N
    Montes, A
    Porras-Montenegro, N
    Duque, CA
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2004, 241 (14): : 3224 - 3230
  • [44] Reversal of circularly polarized luminescence direction and an "on-off" switch driven by exchange between UV light irradiation and the applied direct current electric field
    Yao, Kun
    Liu, Zheng
    Li, Hang
    Xu, Dan
    Zheng, Wen-Hua
    Quan, Yi-Wu
    Cheng, Yi-Xiang
    SCIENCE CHINA-CHEMISTRY, 2022, 65 (10) : 1945 - 1952
  • [45] Reversal of circularly polarized luminescence direction and an “on-off” switch driven by exchange between UV light irradiation and the applied direct current electric field
    Kun Yao
    Zheng Liu
    Hang Li
    Dan Xu
    Wen-Hua Zheng
    Yi-Wu Quan
    Yi-Xiang Cheng
    Science China(Chemistry), 2022, 65 (10) : 1945 - 1952
  • [46] Domain evolution in epitaxial (001) Pb(Zr,Ti)O3 ultrathin films under an electric field applied along the [111] direction
    Sichuga, D.
    Bellaiche, L.
    PHYSICAL REVIEW B, 2012, 85 (21):
  • [47] Reversal of circularly polarized luminescence direction and an “on-off” switch driven by exchange between UV light irradiation and the applied direct current electric field
    Kun Yao
    Zheng Liu
    Hang Li
    Dan Xu
    Wen-Hua Zheng
    Yi-Wu Quan
    Yi-Xiang Cheng
    Science China Chemistry, 2022, 65 : 1945 - 1952
  • [48] Reversal of circularly polarized luminescence direction and an “on-off” switch driven by exchange between UV light irradiation and the applied direct current electric field
    Kun Yao
    Zheng Liu
    Hang Li
    Dan Xu
    WenHua Zheng
    YiWu Quan
    YiXiang Cheng
    Science China(Chemistry) , 2022, (10) : 1945 - 1952
  • [49] Switching between spectral broadening and narrowing of the exciton absorption band of a CH3NH3PbI3 film on altering the polarity of an applied electric field
    Awasthi, Kamlesh
    Kala, Kannankutty
    Rana, Shailesh
    Diau, Eric Wei-Guang
    Ohta, Nobuhiro
    APPLIED PHYSICS LETTERS, 2020, 116 (25)
  • [50] Photorefractive properties of (1-10) and (111)-cut sillenite crystals when external electric field is applied along the direction of the optimum diffraction efficiency
    N.C. Deliolanis
    A.G. Apostolidis
    E.D. Vanidhis
    D.G. Papazoglou
    Applied Physics B, 2002, 75 : 67 - 73
12345