Structure of μ-oxo-bis{{2,2′-[propane-1,3-diylbis (aminomethyl)]diphenolato}oxorhenium(V)}

被引：2
|
作者：
Huang, WT [1 ]
Yao, HH
Chen, BH
Liao, FL
Lo, JM
机构：
[1] Yuanpei Inst Sci & Technol, Dept Radiol Technol, Hsinchu, Taiwan
[2] Taiwan Salt Corp, Tainan, Taiwan
[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
[4] Natl Tsing Hua Univ, Dept Nucl Sci, Hsinchu, Taiwan
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2002年 / 32卷 / 11期
关键词：
oxorhenium(V); hexacoordinate; binuclear; octahedral coordination;
D O I：
10.1023/A:1021192725915
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C34H40N4O7Re2, each of the two Re(V) atoms is hexacoordinated by two amine nitrogens, two phenol oxygens, and two axial oxygens. The compound is a binuclear complex with an O=Re-O-Re=O backbone and nearly octahedral coordination geometry at each Re atom. The Re=O bond distance is 1.720(14) Angstrom and the Re-O bridge bond distance is 1.938(12) Angstrom. The equatorial plane Re-O bond distances are 1.992(14) and 2.012(13) Angstrom, whereas the Re-N bond distances are 2.129(15) and 2.187(16) Angstrom.
引用
收藏
页码：465 / 468
页数：4
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