Effect of the nature of polymer matrix on the process of cholesterol photooxidation in the presence of immobilized tetraphenylporphyrins

被引：2
|
作者：
Glagolev, N. N. [1 ]
Belyaev, V. E. [1 ]
Rzheznikov, V. M. [2 ]
Solov'eva, A. B. [1 ]
Golubovskaya, L. E. [2 ]
Kiryukhin, Yu. I. [3 ]
Luzgina, V. N. [2 ,4 ]
机构：
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia
[2] Inst Expt Endocrinol, Endocrinol Sci Ctr, Moscow 115478, Russia
[3] LY Karpov Phys Chem Res Inst, Moscow 115064, Russia
[4] Lomonosov State Acad Fine Chem Technol, Moscow 119571, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2009年 / 83卷 / 13期
基金：
俄罗斯基础研究基金会;
关键词：
STEROID SERIES; B-NORSTEROIDS;
D O I：
10.1134/S0036024409130317
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It was shown that carrying out the reaction of cholesterol photosensitized oxidation in the presence of porphyrins immobilized on the hydrolyzed copolymer of tetrafluorethylene and H+ form of perfluoro-3,6-dioxo-5-methyl-6-sulfonylfluorideoctene-1 leads to the formation of not previously described new products: 6 beta-phormyl-B-norcholestan-3 beta,5 beta-diol, 6 beta-chlorocholestan-3 beta,5 alpha-diol, cholestan-3 beta,5 alpha,6 beta-triol, and 5 alpha-chlorocholestan-3 beta,6 beta-diol.
引用
收藏
页码：2362 / 2367
页数：6
相关论文
共 32 条
  • [21] Effect of the matrix structure and concentration of polymer-immobilized Ni2+-iminodiacetic acid complexes on retention of IgG1
    Krácaliková, K
    Tishchenko, G
    Bleha, M
    JOURNAL OF BIOCHEMICAL AND BIOPHYSICAL METHODS, 2006, 67 (01): : 7 - 25
  • [22] Effect of Preform Consolidation on the Fracture Toughness of Marine Grade Polymer Matrix Composite Materials Fabricated with a VARTM Process
    Berube, Keith A.
    Lopez-Anido, Roberto A.
    JOURNAL OF ADVANCED MATERIALS, 2011, 43 (01): : 30 - 46
  • [23] Isothermal frontal polymerization: Confirmation of the isothermal nature of the process and the effect of oxygen and polymer seed molecular weight on front propagation
    Evstratova, Svetlana I.
    Antrim, Daniel
    Fillingane, Chip
    Pojman, John A.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (11) : 3601 - 3608
  • [24] Effect of the curing process on the transverse tensile strength of fiber-reinforced polymer matrix lamina using micromechanics computations
    D’Mello R.J.
    Maiarù M.
    Waas A.M.
    Integrating Materials and Manufacturing Innovation, 2015, 4 (01) : 119 - 136
  • [25] TOPOGRAPHICAL NATURE OF THE POLYMER MATRIX AND REACTIVITY OF ATTACHED FUNCTIONAL-GROUPS - EFFECT OF CROSSLINK DENSITY ON THE EFFICIENCY OF SOLID-PHASE HYPOCHLORITE OXIDATIONS
    SREEKUMAR, K
    PILLAI, VNR
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1989, 101 (04): : 335 - 342
  • [26] Effect of Bond Coats on Thermal Shock Resistance of Thermal Barrier Coatings Deposited Onto Polymer Matrix Composites Via Air Plasma Spray Process
    Wenzhi Huang
    Yu Zhao
    Xizhi Fan
    Xiangsheng Meng
    Ying Wang
    Xiaolong Cai
    Xueqiang Cao
    Zhen Wang
    Journal of Thermal Spray Technology, 2013, 22 : 918 - 925
  • [27] Effect of Bond Coats on Thermal Shock Resistance of Thermal Barrier Coatings Deposited Onto Polymer Matrix Composites Via Air Plasma Spray Process
    Huang, Wenzhi
    Zhao, Yu
    Fan, Xizhi
    Meng, Xiangsheng
    Wang, Ying
    Cai, Xiaolong
    Cao, Xueqiang
    Wang, Zhen
    JOURNAL OF THERMAL SPRAY TECHNOLOGY, 2013, 22 (06) : 918 - 925
  • [28] EFFECT OF GLASS FIBER-MATRIX POLYMER INTERACTION ON FATIGUE CHARACTERISTICS OF SHORT GLASS-FIBER-REINFORCED POLY(BUTYLENE TEREPHTHALATE) BASED ON DYNAMIC VISCOELASTIC MEASUREMENT DURING THE FATIGUE PROCESS
    TAKAHARA, A
    MAGOME, T
    KAJIYAMA, T
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1994, 32 (05) : 839 - 849
  • [29] Promoting of non-transition metal alkylation with organyl halides in the presence of binary systems based on an organometallic Compound and a transition metal compound: IV. The effect of nature of the organometallic component of the binary system on the rate of the stationary process
    Eremeev, I. V.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (08) : 1885 - 1895
  • [30] Promoting of non-transition metal alkylation with organyl halides in the presence of binary systems based on an organometallic Compound and a transition metal compound: IV. The effect of nature of the organometallic component of the binary system on the rate of the stationary process
    I. V. Eremeev
    Russian Journal of General Chemistry, 2015, 85 : 1885 - 1895
1234