Effect of the nature of polymer matrix on the process of cholesterol photooxidation in the presence of immobilized tetraphenylporphyrins

被引：2
|
作者：
Glagolev, N. N. [1 ]
Belyaev, V. E. [1 ]
Rzheznikov, V. M. [2 ]
Solov'eva, A. B. [1 ]
Golubovskaya, L. E. [2 ]
Kiryukhin, Yu. I. [3 ]
Luzgina, V. N. [2 ,4 ]
机构：
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia
[2] Inst Expt Endocrinol, Endocrinol Sci Ctr, Moscow 115478, Russia
[3] LY Karpov Phys Chem Res Inst, Moscow 115064, Russia
[4] Lomonosov State Acad Fine Chem Technol, Moscow 119571, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2009年 / 83卷 / 13期
基金：
俄罗斯基础研究基金会;
关键词：
STEROID SERIES; B-NORSTEROIDS;
D O I：
10.1134/S0036024409130317
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It was shown that carrying out the reaction of cholesterol photosensitized oxidation in the presence of porphyrins immobilized on the hydrolyzed copolymer of tetrafluorethylene and H+ form of perfluoro-3,6-dioxo-5-methyl-6-sulfonylfluorideoctene-1 leads to the formation of not previously described new products: 6 beta-phormyl-B-norcholestan-3 beta,5 beta-diol, 6 beta-chlorocholestan-3 beta,5 alpha-diol, cholestan-3 beta,5 alpha,6 beta-triol, and 5 alpha-chlorocholestan-3 beta,6 beta-diol.
引用
收藏
页码：2362 / 2367
页数：6
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