Crystal structure of the molecular inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene with acetone (1:3)

被引：7
|
作者：
Lu, GY [1 ]
Liu, F [1 ]
Liu, YJ [1 ]
He, WJ [1 ]
Li, Q [1 ]
Zhu, LG [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Dept Chem, Nanjing 210093, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 10期
基金：
中国国家自然科学基金;
关键词：
calix[4]arene; acetone; inclusion complex;
D O I：
10.1023/A:1009514026129
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Crystal structure of inclusion complex of 5, 17-di-t-butyl-26, 28-disubstituted calix[4]arene 3 with acetone, [(C54H58N2O6 . CH3COCH3) . 2CH(3)COCH(3)], was determined by X-ray crystallographic analysis. It possesses space group C2/c, with a = 26.277(8), b = 12.967(5), c = 20.355(4) Angstrom, beta = 124.845(14)degrees, and D-calc = 1.173 mg/m(3) for Z = 4. Crystal data indicate that action of one molecule of compound 3 upon three molecules of acetone forms a clathrate intermolecular inclusion complex.
引用
收藏
页码：1121 / 1125
页数：5
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