An active catalytic system for Suzuki Miyaura cross-coupling reactions using low levels of palladium loading

被引:1
|
作者
Yan, Meng-Qi [1 ]
Yuan, Jia [1 ,2 ]
Lan, Fang [1 ]
Zeng, Si-Hao [1 ]
Gao, Meng-Yue [1 ]
Liu, Sheng-Hua [1 ]
Chen, Jian [1 ,2 ]
Yu, Guang-Ao [1 ,2 ]
机构
[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
[2] Cent China Normal Univ, Coll Chem, Chem Biol Ctr, Wuhan 430079, Peoples R China
基金
中国国家自然科学基金;
关键词
HETEROARYL BORONIC ACIDS; PHOSPHINE LIGAND; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; ARYL CHLORIDES; EFFICIENT; PPM; COMPLEXES; AMINATION; NANOPARTICLES;
D O I
10.1039/C7OB00178A
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An easily available Pd(OAc)2/(2-(anthracen-9-0-1H-inden-3-0) d cyclohexylphosphine/toluene/PrOH/ water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.
引用
收藏
页码:3924 / 3929
页数:6
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