An active catalytic system for Suzuki Miyaura cross-coupling reactions using low levels of palladium loading

被引:1
|
作者
Yan, Meng-Qi [1 ]
Yuan, Jia [1 ,2 ]
Lan, Fang [1 ]
Zeng, Si-Hao [1 ]
Gao, Meng-Yue [1 ]
Liu, Sheng-Hua [1 ]
Chen, Jian [1 ,2 ]
Yu, Guang-Ao [1 ,2 ]
机构
[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
[2] Cent China Normal Univ, Coll Chem, Chem Biol Ctr, Wuhan 430079, Peoples R China
基金
中国国家自然科学基金;
关键词
HETEROARYL BORONIC ACIDS; PHOSPHINE LIGAND; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; ARYL CHLORIDES; EFFICIENT; PPM; COMPLEXES; AMINATION; NANOPARTICLES;
D O I
10.1039/C7OB00178A
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An easily available Pd(OAc)2/(2-(anthracen-9-0-1H-inden-3-0) d cyclohexylphosphine/toluene/PrOH/ water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.
引用
收藏
页码:3924 / 3929
页数:6
相关论文
共 50 条
  • [21] Suzuki-Miyaura Cross-Coupling Reactions of Unprotected Haloimidazoles
    Tan, Jiajing
    Chen, Yonggang
    Li, Hongmei
    Yasuda, Nobuyoshi
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (18): : 8871 - 8876
  • [22] Orbital phase in Suzuki-Miyaura cross-coupling reactions
    Inagaki, Satoshi
    Ikeda, Hirotaka
    TETRAHEDRON LETTERS, 2014, 55 (14) : 2223 - 2225
  • [23] 3D Printed Palladium Catalyst for Suzuki-Miyaura Cross-coupling Reactions
    Bulatov, Evgeny
    Lahtinen, Elmeri
    Kivijarvi, Lauri
    Hey-Hawkins, Evamarie
    Haukka, Matti
    CHEMCATCHEM, 2020, 12 (19) : 4831 - 4838
  • [24] Suzuki-Miyaura cross-coupling reactions in water using in situ generated palladium(II)-phosphazane complexes
    Amini, Mojtaba
    Tarassoli, Abbas
    Yousefi, Saeed
    Delsouz-Hafshejani, Sepideh
    Bigdeli, Mina
    Salehifar, Mahnaz
    CHINESE CHEMICAL LETTERS, 2014, 25 (01) : 166 - 168
  • [25] Plasmonic catalysis for the Suzuki-Miyaura cross-coupling reaction using palladium nanoflowers
    Sarhid, Iyad
    Abdellah, Ibrahim
    Martini, Cyril
    Hu, Vincent
    Dragoe, Diana
    Beaunier, Patricia
    Lampre, Isabelle
    Remita, Hynd
    NEW JOURNAL OF CHEMISTRY, 2019, 43 (11) : 4349 - 4355
  • [26] Substituted 2-(2′-pyridyl)benzimidazole palladium(II) complexes as an efficient catalytic system for Suzuki-Miyaura cross-coupling reactions
    Ulusoy, Mahmut
    Oncel, Nurdal
    Aytar, Emine
    TURKISH JOURNAL OF CHEMISTRY, 2015, 39 (06) : 1289 - 1299
  • [27] Suzuki-Miyaura cross-coupling with quasi-heterogeneous palladium
    Conlon, DA
    Pipik, B
    Ferdinand, S
    LeBlond, CR
    Sowa, JR
    Izzo, B
    Collins, P
    Ho, GJ
    Williams, JM
    Shi, YJ
    Sun, YK
    ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (08) : 931 - 935
  • [28] Minimisation of palladium content in Suzuki cross-coupling reactions
    Tye, Heather
    Whittaker, Mark
    Ramdeehul, Shailesh
    COMBINATORIAL CHEMISTRY & HIGH THROUGHPUT SCREENING, 2006, 9 (09) : 703 - 710
  • [29] Palladium(II) Complexes with Chelating Biscarbene Ligands in the Catalytic Suzuki-Miyaura Cross-Coupling Reaction
    Micksch, Maik
    Strassner, Thomas
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (35) : 5872 - 5880
  • [30] A simple and highly efficient catalytic system for Suzuki cross-coupling using ligandless palladium chloride
    Tao, XC
    Zhao, YY
    Shen, D
    SYNLETT, 2004, (02) : 359 - 361