Synthesis, structure and reactivity of [Yb(eta-C(5)Me(5)){Si(SiMe(3))(3)}(thf)(2)]

被引：40
|
作者：
Corradi, MM [1 ]
Frankland, AD [1 ]
Hitchcock, P [1 ]
Lappert, MF [1 ]
Lawless, GA [1 ]
机构：
[1] UNIV SUSSEX,CHEM LAB,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 20期
关键词：
D O I：
10.1039/cc9960002323
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of [Yb(eta C(5)Me(5))(2)(OEt(2))] With 1 equiv, of [Li{Si(SiMe(3))(3)} (thf)(3)] in toluene affords [Yb(eta-C(5)Me(5)){Si-(SiMe(3))(3)}(thf)(2)] 1 in high yield; a single-crystal X-ray analysis and multinuclear Yb-171 and Si-29 NMR spectroscopic data for 1 are reported.
引用
收藏
页码：2323 / 2324
页数：2
相关论文
共 50 条
  • [41] Organopolysilane oligomers bearing transition-metal moieties: Synthesis, reactivities and molecular structure of [eta(5)-Me(3)SiM(2)SiC(5)H(4)(CO)Fe(CO)(2)Fe(CO)-eta(5)-C(5)H(4)SiMe(2)SiMe(3)]
    Sun, HL
    Zhou, XZ
    Yao, XK
    Wang, HG
    POLYHEDRON, 1996, 15 (24) : 4489 - 4495
  • [42] Synthesis and crystal structure of (C5Me4SiMe3)[(iPrN)2CCH2SiMe3]2Y
    Chen Jue
    Wang Xiulian
    Luo Yunjie
    Yao Yingming
    JOURNAL OF RARE EARTHS, 2009, 27 (01) : 18 - 21
  • [43] Di- and triphospha-ferrocenes: Crystal and molecular structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(3)(t)Bu(3)P(2))] and of the adducts [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Mo(CO)(5)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))W(CO)(5)]
    Muller, C
    Bartsch, R
    Fischer, A
    Jones, PG
    Schmutzler, R
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 512 (1-2) : 141 - 148
  • [44] Synthesis and crystal structure of(C5Me4SiMe3)[(~iPrN)2CCH2SiMe3]2Y
    陈珏
    王秀莲
    罗云杰
    姚英明
    JournalofRareEarths, 2009, 27 (01) : 18 - 21
  • [45] Synthesis and solid-state structure of Zn(η5-C5Me4SiMe3)(η1-C5Me4SiMe3), a zincocene with nonparallel cyclopentadienyl rings
    Fernández, R
    Resa, I
    del Río, D
    Carmona, E
    Gutiérrez-Puebla, E
    Monge, A
    ORGANOMETALLICS, 2003, 22 (03) : 381 - 383
  • [46] Mono(pentamethylcyclopentadienyl)uranium(III) complexes:: Synthesis, properties, and X-ray structures of (η-C5Me5)UI2(THF)3, (η-C5Me5)UI2(py)3, and (η-C5Me5)U[N(SiMe3)2]2
    Avens, LR
    Burns, CJ
    Butcher, RJ
    Clark, DL
    Gordon, JC
    Schake, AR
    Scott, BL
    Watkin, JG
    Zwick, BD
    ORGANOMETALLICS, 2000, 19 (04) : 451 - 457
  • [47] DIALKYLAMIDO DERIVATIVES OF [(ETA-5-C5ME5)TICL3], [((ETA-5-C5ME5)TICL2)2(MU-O)] AND [((ETA-5-C5ME5)TICL)3(MU-O)3] - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5ME5)TI(NME2)3]
    MARTIN, A
    MENA, M
    YELAMOS, C
    SERRANO, R
    RAITHBY, PR
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 467 (01) : 79 - 84
  • [48] SYNTHESIS OF [PD2(ETA-5-C5ME5)2(MU-CO)2] AND ITS REACTION WITH ACIDS - STRUCTURE OF [PD3(ETA-5-C5ME5)3(MU-3-CO)2]+[CF3SO3]-
    BOAG, NM
    BOUCHER, D
    DAVIES, JA
    MILLER, RW
    PINKERTON, AA
    SYED, R
    ORGANOMETALLICS, 1988, 7 (03) : 791 - 792
  • [49] Dicyclopentadienyl titanium and zirconium complexes with the double bridged bis(dimethylsilanodiyl) dicyclopentadienyl [(Me(2)Si)(2)(eta(5)-C5H3)(2)](2-) ligand: X-ray molecular structure of [Ti{(SiMe(2))(2)(eta(5)-C5H3)(2)}Me(2)]
    Cano, A
    Cuenca, T
    GomezSal, P
    Manzanero, A
    Royo, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 526 (02) : 227 - 235
  • [50] THE 1ST UNSUBSTITUTED METALLABENZENE COMPLEX [RU2(ETA-5-C5ME5)2(ETA-2,ETA-5-C5H5)(SIME3)]
    LIN, WB
    WILSON, SR
    GIROLAMI, GS
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 284 - 285
12345