Synthesis, structure and reactivity of [Yb(eta-C(5)Me(5)){Si(SiMe(3))(3)}(thf)(2)]

被引：40

作者：

Corradi, MM ^{[1
]}

Frankland, AD ^{[1
]}

Hitchcock, P ^{[1
]}

Lappert, MF ^{[1
]}

Lawless, GA ^{[1
]}

机构：

[1] UNIV SUSSEX,CHEM LAB,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 20期

关键词：

D O I：

10.1039/cc9960002323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Yb(eta C(5)Me(5))(2)(OEt(2))] With 1 equiv, of [Li{Si(SiMe(3))(3)} (thf)(3)] in toluene affords [Yb(eta-C(5)Me(5)){Si-(SiMe(3))(3)}(thf)(2)] 1 in high yield; a single-crystal X-ray analysis and multinuclear Yb-171 and Si-29 NMR spectroscopic data for 1 are reported.

引用

页码：2323 / 2324

页数：2

共 50 条

[31] ON THE REACTIVITY OF (ETA-5-C5ME5)(CO)2FEP(SIME3)2 TOWARD P-CHLOROMETHYLENE PHOSPHANES
WEBER, L
KIRCHHOFF, R
STAMMLER, HG
NEUMANN, B
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (10): : 1725 - 1729
[32] STABLE SILACYCLOPENTADIENYL COMPLEXES OF RUTHENIUM - (ETA(5)-C(5)ME(5))RU[ETA(5)-ME(4)C(4)SISI(SIME(3))(3)] AND X-RAY STRUCTURE OF ITS PROTONATED FORM
FREEMAN, WP
TILLEY, TD
RHEINGOLD, AL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) : 8428 - 8429
[33] Thermal decomposition of [(eta(5)-C(5)Me(5))TiMe(3)]: Synthesis and structure of the methylidyne cubane [{(eta(5)-C(5)Me(5))Ti}(4)(mu(3)-CH)(4)]
Andres, R
GomezSal, P
deJesus, E
Martin, A
Mena, M
Yelamos, C
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (1-2) : 115 - 117
[34] SYNTHESIS AND STRUCTURE OF [(C5ME5)2SM(THF)]2(MU-ETA(1)ETA(1)-C2)
EVANS, WJ
RABE, GW
ZILLER, JW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 483 (1-2) : 21 - 25
[35] SYNTHESIS AND CHARACTERIZATION OF [(ETA-C5ME5)RU(MU,ETA-C5ME5)RU(ETA-C5ME5)]+[A]-, [A]-=TCNE, TCNQ, C3[C(CN)2]3 - CRYSTAL-STRUCTURE OF THE ONE-DIMENSIONAL SALT [ETA-C5ME5)RU(MU,ETA-C5ME5)RU(ETA-C5ME5)]+[TCNE]-
OHARE, D
BROOKES, J
WATKIN, DJ
JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (04) : 691 - 697
[36] SYNTHESIS, STRUCTURE, AND LIGAND BEHAVIOR OF THE 1,2-DIPHOSPHAFERROCENE [(ETA(5)-1,3-TBU(2)C(5)H(3))(ETA(5)-(3,4-(ME(3)SIO)(2)-5-(ME(3)SI)P2C(3))FE]
WEBER, L
SOMMER, O
STAMMLER, HG
NEUMANN, B
KOLLE, U
CHEMISCHE BERICHTE, 1995, 128 (07) : 665 - 671
[37] SYNTHESIS OF MONOMERIC PERMETHYLYTTROCENE DERIVATIVES - THE CRYSTAL-STRUCTURES OF ETA-5-C5H5YN(SIME3)2 AND ETA-5-C5H5YCH(SIME3)2
DENHAAN, KH
DEBOER, JL
TEUBEN, JH
SPEK, AL
KOJICPRODIC, B
HAYS, GR
HUIS, R
ORGANOMETALLICS, 1986, 5 (08) : 1726 - 1733
[38] A FACILE SYNTHESIS OF IMINOSILANES - CRYSTAL-STRUCTURE OF (ME3C)2(THF)SI=N-SIME(CME3)2
WALTER, S
KLINGEBIEL, U
SCHMIDTBASE, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) : 319 - 326
[39] Synthesis and structural characterization of complexes of the {Cp(*)Rh} and {MeRe} cores with pyridine-2-thiol ligand types. Structures of MeReO(eta(2)-2-SC5H3N-3-SiMe)(2) and (eta(5)-Me(5)C(5))Rh(eta(2)-2-SC5H3N-3-SiMe(3))(eta(1)-2-SC5H3N-3-SiMe(3))
Kettler, PB
Chang, Y
Rose, D
Zubieta, J
Abrams, MJ
INORGANICA CHIMICA ACTA, 1996, 244 (02) : 199 - 205
[40] THERMALLY STABLE ALLYL ZIRCONIUM HALIDE COMPOUNDS - SYNTHESIS, CRYSTAL-STRUCTURE, AND DYNAMICS OF (ETA-5-C5ME5)(ETA-3-1,2,3-ME3ALLYL)ZRBR2 AND (ETA-5-C5ME5)(ETA-3-1,1,2-ME3ALLYL)ZRBR2
LARSON, EJ
VANDORT, PC
DAILEY, JS
LAKANEN, JR
PEDERSON, LM
SILVER, ME
HUFFMAN, JC
RUSSO, SO
ORGANOMETALLICS, 1987, 6 (10) : 2141 - 2146

← 1 2 3 4 5 →