Catalytic activities enhanced by abundant structural defects and balanced N distribution of N-doped graphene in oxygen reduction reaction

被引：58

作者：

Bai, Xiaogong ^{[1
]}

Shi, Yantao ^{[1
]}

Guo, Jiahao ^{[1
]}

Gao, Liguo ^{[2
]}

Wang, Kai ^{[1
]}

Du, Yi ^{[1
]}

Ma, Tingli ^{[2
,3
]}

机构：

[1] Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] Dalian Univ Technol, Sch Petr & Chem Engn, Panjin 124221, Peoples R China

[3] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Kitakyushu, Fukuoka 8080196, Japan

来源：

JOURNAL OF POWER SOURCES | 2016年 / 306卷

基金：

中国国家自然科学基金; 对外科技合作项目（国际科技项目）;

关键词：

N-doping graphene; Oxygen reduction reaction; N-distribution; Structural defects; HIGH ELECTROCATALYTIC ACTIVITY; METAL-FREE CATALYST; ONE-POT SYNTHESIS; NITROGEN; METHANOL; ALKALINE;

D O I：

10.1016/j.jpowsour.2015.10.081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

N-doped graphene (NG) is a promising candidate for oxygen reduction reaction (ORR) in the cathode of fuel cells. However, the catalytic activity of NG is lower than that of commercial Pt/C in alkaline and acidic media. In this study, NG samples were obtained using urea as N source. The structural defects and N distribution in the samples were adjusted by regulating the pyrolysis temperature. The new NG type exhibited remarkable catalytic activities for ORR in both alkaline and acidic media. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：85 / 91

页数：7

共 50 条

[41] N-doped mesoporous carbon spheres as the oxygen reduction reaction catalysts
Yang, Tianyu
Liu, Jian
Zhou, Ruifeng
Chen, Zhigang
Xu, Hongyi
Qiao, Shi Zhang
Monteiro, Michael J.
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) : 18139 - 18146
[42] N-doped graphene as catalysts for oxygen reduction and oxygen evolution reactions: Theoretical considerations
Li, Mingtao
Zhang, Lipeng
Xu, Quan
Niu, Jianbing
Xia, Zhenhai
JOURNAL OF CATALYSIS, 2014, 314 : 66 - 72
[43] N-doped graphene/carbon composite as non-precious metal electrocatalyst for oxygen reduction reaction
Liu, Qing
Zhang, Heyou
Zhong, Huawei
Zhang, Shiming
Chen, Shengli
ELECTROCHIMICA ACTA, 2012, 81 : 313 - 320
[44] Towards new routes to increase the electrocatalytic activity for oxygen reduction reaction of n-doped graphene nanofibers
Paton-Carrero, A.
de la Osa, A. R.
Sanchez, P.
Rodriguez-Gomez, A.
Romero, A.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 878
[45] Nanocomposite of N-Doped TiO2 Nanorods and Graphene as an Effective Electrocatalyst for the Oxygen Reduction Reaction
Yuan, Wenjing
Li, Juchuan
Wang, Likun
Chen, Ping
Xie, Anjian
Shen, Yuhua
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) : 21978 - 21985
[46] First principles study of oxygen reduction reaction mechanisms on N-doped graphene with a transition metal support
Noh, Seung Hyo
Kwak, Do Hyun
Seo, Min Ho
Ohsaka, Takeo
Han, Byungchan
ELECTROCHIMICA ACTA, 2014, 140 : 225 - 231
[47] Theoretical screening of the metal-nonmetal pair anchored on N-doped graphene for the oxygen reduction reaction
Zhang, Ji
Zhang, Peng
Yu, Aimin
Li, Dong-sheng
Sun, Chenghua
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (43) : 27332 - 27337
[48] NiCo2O4/N-doped graphene as an advanced electrocatalyst for oxygen reduction reaction
Zhang, Hui
Li, Huiyong
Wang, Haiyan
He, Kejian
Wang, Shuangyin
Tang, Yougen
Chen, Jiajie
JOURNAL OF POWER SOURCES, 2015, 280 : 640 - 648
[49] Theoretical investigation on the Ni atom-pair supported by N-doped graphene for the oxygen reduction reaction
Zhang, Ji
Li, Shichang
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2022, 1209
[50] The synergetic effect of N-doped graphene and silver nanowires for high electrocatalytic performance in the oxygen reduction reaction
Yu, Dongbo
Yao, Jianfeng
Qiu, Ling
Wu, Yuzhou
Li, Lunxi
Feng, Yi
Liu, Qi
Li, Dan
Wang, Huanting
RSC ADVANCES, 2013, 3 (29): : 11552 - 11555

← 1 2 3 4 5 →